{"title":"稀土改性还原氧化石墨烯增强银铜钛复合钎焊填料,用于钎焊 C/C 复合材料","authors":"Liang Wu, Yue Li, Jin-wei Chen, Rui Zhang, Qian-kun Zhang, Yi-feng Xiao","doi":"10.1007/s11771-024-5637-0","DOIUrl":null,"url":null,"abstract":"<p>In order to solve the formation of brittle compounds in brazed joints, an innovative rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler was designed to achieve brazed joints with Ag-Cu eutectic as the main organization almost free of brittle compounds, and at the same time, the dispersion of graphene in the joint interfaces was improved. Microanalysis and discussion of the brazing fillers with and without Ce modification showed that the Ce modified reduced graphene oxide was more uniformly dispersed in the brazing fillers. The interfacial microstructures of C/C composites-C/C composites joints with and without Ce modified brazing fillers were compared, and the effect of graphene content on the organization and properties of the joints was investigated. The results showed that the shear strength of the joints was significantly enhanced by using Ce modified brazing fillers. When the graphene content was 0.5 wt.%, the average shear strength of the brazed joints obtained by using Ce modified brazing fillers was 31.82 MPa, increased by 50%.</p>","PeriodicalId":15231,"journal":{"name":"Journal of Central South University","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler for brazing C/C composites\",\"authors\":\"Liang Wu, Yue Li, Jin-wei Chen, Rui Zhang, Qian-kun Zhang, Yi-feng Xiao\",\"doi\":\"10.1007/s11771-024-5637-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In order to solve the formation of brittle compounds in brazed joints, an innovative rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler was designed to achieve brazed joints with Ag-Cu eutectic as the main organization almost free of brittle compounds, and at the same time, the dispersion of graphene in the joint interfaces was improved. Microanalysis and discussion of the brazing fillers with and without Ce modification showed that the Ce modified reduced graphene oxide was more uniformly dispersed in the brazing fillers. The interfacial microstructures of C/C composites-C/C composites joints with and without Ce modified brazing fillers were compared, and the effect of graphene content on the organization and properties of the joints was investigated. The results showed that the shear strength of the joints was significantly enhanced by using Ce modified brazing fillers. When the graphene content was 0.5 wt.%, the average shear strength of the brazed joints obtained by using Ce modified brazing fillers was 31.82 MPa, increased by 50%.</p>\",\"PeriodicalId\":15231,\"journal\":{\"name\":\"Journal of Central South University\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-06-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Central South University\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11771-024-5637-0\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Central South University","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11771-024-5637-0","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
为了解决钎焊接头中脆性化合物的形成问题,设计了一种创新的稀土改性还原氧化石墨烯增强银铜钛复合钎焊填料,实现了以银铜共晶为主要组织的钎焊接头几乎不产生脆性化合物,同时提高了石墨烯在接头界面中的分散性。对有无 Ce 改性的钎焊填料进行的显微分析和讨论表明,Ce 改性的还原氧化石墨烯在钎焊填料中的分散更均匀。比较了有和无 Ce 改性钎焊填料的 C/C 复合材料-C/C 复合材料接头的界面微观结构,并研究了石墨烯含量对接头组织和性能的影响。结果表明,使用 Ce 改性钎焊填料可显著提高接头的剪切强度。当石墨烯含量为 0.5 wt.%时,使用 Ce 改性钎料获得的钎焊接头平均剪切强度为 31.82 MPa,提高了 50%。
In order to solve the formation of brittle compounds in brazed joints, an innovative rare earth modified reduced graphene oxide reinforced AgCuTi composite brazing filler was designed to achieve brazed joints with Ag-Cu eutectic as the main organization almost free of brittle compounds, and at the same time, the dispersion of graphene in the joint interfaces was improved. Microanalysis and discussion of the brazing fillers with and without Ce modification showed that the Ce modified reduced graphene oxide was more uniformly dispersed in the brazing fillers. The interfacial microstructures of C/C composites-C/C composites joints with and without Ce modified brazing fillers were compared, and the effect of graphene content on the organization and properties of the joints was investigated. The results showed that the shear strength of the joints was significantly enhanced by using Ce modified brazing fillers. When the graphene content was 0.5 wt.%, the average shear strength of the brazed joints obtained by using Ce modified brazing fillers was 31.82 MPa, increased by 50%.
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