I. O. Hnatenko, I. V. Andreiev, S. O. Lysovenko, O. S. Roik, M. O. Tsysar, T. O. Kosenchuk
{"title":"高压和高温导致的 WC-Co 硬质合金显微结构和性能变化","authors":"I. O. Hnatenko, I. V. Andreiev, S. O. Lysovenko, O. S. Roik, M. O. Tsysar, T. O. Kosenchuk","doi":"10.1007/s11003-024-00820-8","DOIUrl":null,"url":null,"abstract":"<p>The change in the structure and physicomechanical properties of sintered binding WC–6Co, and WC–15Co cemented carbides because of the action of high pressure (8 GPa) and high temperature (HPHT) in the Toroid installation is investigated. It is established that as a result of HPHT treatment at temperatures above the melting point of the metal binding phase, there is a decrease in the coercive force of the experimental alloys due to the growth of the carbide grain of the alloy. In alloys with a higher content of the binding phase, Co<sub>3</sub>W, Co<sub>6</sub>W<sub>6</sub>C intermetallic phases, and oxide of the Co<sub>2</sub>O<sub>3</sub> type are formed. The hardness of the HPHT treated WC–6Co alloy samples decreases due to the growth of the alloy carbide grain, and the hardness of the treated WC–15Co samples increases due to the formation of intermetallic phases.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Change of Microstructure and Properties of WC–Co Cemented Carbides as a Result of High Pressure and Temperature\",\"authors\":\"I. O. Hnatenko, I. V. Andreiev, S. O. Lysovenko, O. S. Roik, M. O. Tsysar, T. O. Kosenchuk\",\"doi\":\"10.1007/s11003-024-00820-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The change in the structure and physicomechanical properties of sintered binding WC–6Co, and WC–15Co cemented carbides because of the action of high pressure (8 GPa) and high temperature (HPHT) in the Toroid installation is investigated. It is established that as a result of HPHT treatment at temperatures above the melting point of the metal binding phase, there is a decrease in the coercive force of the experimental alloys due to the growth of the carbide grain of the alloy. In alloys with a higher content of the binding phase, Co<sub>3</sub>W, Co<sub>6</sub>W<sub>6</sub>C intermetallic phases, and oxide of the Co<sub>2</sub>O<sub>3</sub> type are formed. The hardness of the HPHT treated WC–6Co alloy samples decreases due to the growth of the alloy carbide grain, and the hardness of the treated WC–15Co samples increases due to the formation of intermetallic phases.</p>\",\"PeriodicalId\":18230,\"journal\":{\"name\":\"Materials Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2024-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s11003-024-00820-8\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s11003-024-00820-8","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Change of Microstructure and Properties of WC–Co Cemented Carbides as a Result of High Pressure and Temperature
The change in the structure and physicomechanical properties of sintered binding WC–6Co, and WC–15Co cemented carbides because of the action of high pressure (8 GPa) and high temperature (HPHT) in the Toroid installation is investigated. It is established that as a result of HPHT treatment at temperatures above the melting point of the metal binding phase, there is a decrease in the coercive force of the experimental alloys due to the growth of the carbide grain of the alloy. In alloys with a higher content of the binding phase, Co3W, Co6W6C intermetallic phases, and oxide of the Co2O3 type are formed. The hardness of the HPHT treated WC–6Co alloy samples decreases due to the growth of the alloy carbide grain, and the hardness of the treated WC–15Co samples increases due to the formation of intermetallic phases.
期刊介绍:
Materials Science reports on current research into such problems as cracking, fatigue and fracture, especially in active environments as well as corrosion and anticorrosion protection of structural metallic and polymer materials, and the development of new materials.