{"title":"使用 Cacumen Platycladi 提取物作为还原剂制备氧化 2-苯基乙醇的 Au/TiO2 催化剂","authors":"Jiali Xiao, Longsheng Zhou, Dangqin Jin, Hui Zhou, Dongfan Liu, Bingyun Zheng","doi":"10.1134/S0965544124030125","DOIUrl":null,"url":null,"abstract":"<p>A Supported gold catalyst was prepared by reduction of HAuCl<sub>4</sub> with the Cacumen Platycladi extract. This catalyst was then used for oxidation of 2-phenylethyl alcohol in a model reaction. Our study evaluated the effect of various preparation conditions, including the Au loading ratio and calcination temperature. Additionally, we explored the influence of the reaction temperature and reaction time on the catalytic performance of a Au/TiO<sub>2</sub> catalyst. Our experimental findings revealed notable results for the Au/TiO<sub>2</sub> catalyst characterized by the Au loading of 1.3 wt % and calcinated at 400°C. Under specific reaction conditions (0.3 g catalyst, 220°C, 3.0 MPa, 2.5 h), the conversion of 2-phenylethyl alcohol reached 45.3 and a 59.6% selectivity and a 27.0% yield of the target product (phenylacetaldehyde). In addition, catalytic performance remained stable after 8 repeated uses.</p>","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 2","pages":"322 - 329"},"PeriodicalIF":1.3000,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of the Au/TiO2 Catalyst for the Oxidation of 2-Phenylethyl Alcohol using a Cacumen Platycladi Extract as a Reducing Agent\",\"authors\":\"Jiali Xiao, Longsheng Zhou, Dangqin Jin, Hui Zhou, Dongfan Liu, Bingyun Zheng\",\"doi\":\"10.1134/S0965544124030125\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A Supported gold catalyst was prepared by reduction of HAuCl<sub>4</sub> with the Cacumen Platycladi extract. This catalyst was then used for oxidation of 2-phenylethyl alcohol in a model reaction. Our study evaluated the effect of various preparation conditions, including the Au loading ratio and calcination temperature. Additionally, we explored the influence of the reaction temperature and reaction time on the catalytic performance of a Au/TiO<sub>2</sub> catalyst. Our experimental findings revealed notable results for the Au/TiO<sub>2</sub> catalyst characterized by the Au loading of 1.3 wt % and calcinated at 400°C. Under specific reaction conditions (0.3 g catalyst, 220°C, 3.0 MPa, 2.5 h), the conversion of 2-phenylethyl alcohol reached 45.3 and a 59.6% selectivity and a 27.0% yield of the target product (phenylacetaldehyde). In addition, catalytic performance remained stable after 8 repeated uses.</p>\",\"PeriodicalId\":725,\"journal\":{\"name\":\"Petroleum Chemistry\",\"volume\":\"64 2\",\"pages\":\"322 - 329\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-06-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petroleum Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0965544124030125\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0965544124030125","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Preparation of the Au/TiO2 Catalyst for the Oxidation of 2-Phenylethyl Alcohol using a Cacumen Platycladi Extract as a Reducing Agent
A Supported gold catalyst was prepared by reduction of HAuCl4 with the Cacumen Platycladi extract. This catalyst was then used for oxidation of 2-phenylethyl alcohol in a model reaction. Our study evaluated the effect of various preparation conditions, including the Au loading ratio and calcination temperature. Additionally, we explored the influence of the reaction temperature and reaction time on the catalytic performance of a Au/TiO2 catalyst. Our experimental findings revealed notable results for the Au/TiO2 catalyst characterized by the Au loading of 1.3 wt % and calcinated at 400°C. Under specific reaction conditions (0.3 g catalyst, 220°C, 3.0 MPa, 2.5 h), the conversion of 2-phenylethyl alcohol reached 45.3 and a 59.6% selectivity and a 27.0% yield of the target product (phenylacetaldehyde). In addition, catalytic performance remained stable after 8 repeated uses.
期刊介绍：
Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas.
Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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