在出现相变时稳定不利的密度差

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Lewis Johns, Ranga Narayanan
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引用次数: 0

摘要

给定多孔固体中处于平衡状态的两相,在重力场中重相位于轻相之上,我们通过从下往上加热来稳定这种不利的密度排列,并推导出温度梯度必须有多大才能达到这一目的的公式。输入的温度梯度对我们系统的稳定性有两种影响。它对热对流的影响是破坏稳定,而对表面热传导的影响是稳定。通过关注零增长率的情况,我们得到了输入温度梯度的临界值,因为它取决于多孔固体的渗透性、整个表面的密度差、约束我们系统的平面之间的距离以及物理特性。我们的问题与贝纳德问题(有两个、一个或没有临界点)和瑞利-泰勒问题(没有临界点)都有联系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Stabilizing an adverse density difference in the presence of phase change

Stabilizing an adverse density difference in the presence of phase change

Given two phases in equilibrium in a porous solid, the heavy phase lying above the light phase in a gravitational field, we stabilize this adverse density arrangement by heating from below and derive a formula for how steep the temperature gradient must be to do this. The input temperature gradient has two effects on the stability of our system. Its effect on the heat convection is destabilizing, its effect on the heat conduction at the surface is stabilizing. By directing our attention to the case of zero growth rate, we obtain the critical value of the input temperature gradient as it depends on the permeability of the porous solid, the density difference across the surface, the distance between the planes bounding our system, and the physical properties. Our problem makes connections to the Bénard problem where it has two, one, or no critical points, and to the Rayleigh–Taylor problem where it has no critical points.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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