亚氨基-λ3-碘烷催化的 N-三烯丙基醛亚胺的合成

IF 4.6 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-07-01 DOI:10.1039/D4QO00875H

Shun Sunagawa, Yoko Tezuka, Akira Tsubouchi, Akira Yoshimura and Akio Saito

引用次数: 0

摘要

我们报告了利用由碘代芳烃前催化剂和三氟甲酰胺原位生成的亚氨基-λ3-碘烷，从醛类和三氟甲酰胺催化合成 N-三氟烯丙基醛亚胺的过程。在本反应中，亚氨基-λ3-碘烷作为酸碱协同催化剂激活了醛和三氟甲酰胺。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane†

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Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane†

We report a catalytic synthesis of N-triflyl aldimines from aldehydes and triflylamide using imino-λ³-iodane generated in situ from an iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ³-iodane works as an acid–base cooperative catalyst to activate aldehydes and triflylamide.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.