M. Ramya, H. S. Lalithamba, Dalli Kumari, G. Nagendra
{"title":"利用凤梨绿色合成氧化镍纳米颗粒及其在合成 N-Fmoc/Cbz 保护的氨基酸衍生硫化物及其生物学研究中的催化用途","authors":"M. Ramya, H. S. Lalithamba, Dalli Kumari, G. Nagendra","doi":"10.2174/0122133372305191240528115104","DOIUrl":null,"url":null,"abstract":"\n\nSynthesis of NiO nanoparticles using environmentally friendly Pongamia pinnata\nseeds as a source of fuel was demonstrated using a solution combustion approach.\n\n\n\nThe protocol for the synthesis of NiO NPs is simple and efficient. NiO NPs were utilized as\nthe catalyst for the synthesis of N-protected aminoalkyl sulfides from N-protected alkyl thiols and\nbromo esters of amino acids.\n\n\n\nThe NiO NPs were characterized using XRD, SEM, and EDX techniques. N-protected aminoalkyl\nsulfides were characterized by HRMS, 1H, and 13C NMR techniques and were evaluated for\ntheir in vitro antifungal activities, against A. Niger using Fluconazole as a standard.\n\n\n\nThe current study presents an effective approach for synthesizing a new class of sulfides\nfrom N-protected aminoalkyl thiols and bromomethyl esters in the presence of nano NiO as a catalyst.\n","PeriodicalId":10945,"journal":{"name":"Current Organocatalysis","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Green Synthesis of NiO Nanoparticles using Pongamia pinnata and their\\nCatalytic Utility in the Snthesis of N-Fmoc/Cbz-protected Amino Acid\\nDerived Sulfides and their Biological Investigations\",\"authors\":\"M. Ramya, H. S. Lalithamba, Dalli Kumari, G. Nagendra\",\"doi\":\"10.2174/0122133372305191240528115104\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n\\nSynthesis of NiO nanoparticles using environmentally friendly Pongamia pinnata\\nseeds as a source of fuel was demonstrated using a solution combustion approach.\\n\\n\\n\\nThe protocol for the synthesis of NiO NPs is simple and efficient. NiO NPs were utilized as\\nthe catalyst for the synthesis of N-protected aminoalkyl sulfides from N-protected alkyl thiols and\\nbromo esters of amino acids.\\n\\n\\n\\nThe NiO NPs were characterized using XRD, SEM, and EDX techniques. N-protected aminoalkyl\\nsulfides were characterized by HRMS, 1H, and 13C NMR techniques and were evaluated for\\ntheir in vitro antifungal activities, against A. Niger using Fluconazole as a standard.\\n\\n\\n\\nThe current study presents an effective approach for synthesizing a new class of sulfides\\nfrom N-protected aminoalkyl thiols and bromomethyl esters in the presence of nano NiO as a catalyst.\\n\",\"PeriodicalId\":10945,\"journal\":{\"name\":\"Current Organocatalysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-06-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Organocatalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/0122133372305191240528115104\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Organocatalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/0122133372305191240528115104","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Green Synthesis of NiO Nanoparticles using Pongamia pinnata and their
Catalytic Utility in the Snthesis of N-Fmoc/Cbz-protected Amino Acid
Derived Sulfides and their Biological Investigations
Synthesis of NiO nanoparticles using environmentally friendly Pongamia pinnata
seeds as a source of fuel was demonstrated using a solution combustion approach.
The protocol for the synthesis of NiO NPs is simple and efficient. NiO NPs were utilized as
the catalyst for the synthesis of N-protected aminoalkyl sulfides from N-protected alkyl thiols and
bromo esters of amino acids.
The NiO NPs were characterized using XRD, SEM, and EDX techniques. N-protected aminoalkyl
sulfides were characterized by HRMS, 1H, and 13C NMR techniques and were evaluated for
their in vitro antifungal activities, against A. Niger using Fluconazole as a standard.
The current study presents an effective approach for synthesizing a new class of sulfides
from N-protected aminoalkyl thiols and bromomethyl esters in the presence of nano NiO as a catalyst.
期刊介绍:
Current Organocatalysis is an international peer-reviewed journal that publishes significant research in all areas of organocatalysis. The journal covers organo homogeneous/heterogeneous catalysis, innovative mechanistic studies and kinetics of organocatalytic processes focusing on practical, theoretical and computational aspects. It also includes potential applications of organocatalysts in the fields of drug discovery, synthesis of novel molecules, synthetic method development, green chemistry and chemoenzymatic reactions. This journal also accepts papers on methods, reagents, and mechanism of a synthetic process and technology pertaining to chemistry. Moreover, this journal features full-length/mini review articles within organocatalysis and synthetic chemistry. It is the premier source of organocatalysis and synthetic methods related information for chemists, biologists and engineers pursuing research in industry and academia.