通过化学途径合成的多功能 Bi12GeO20 化合物的研究

Anup Kumar, Manish K. Verma, Biswajeet Jena, D. Tiwary, N. Singh, Kamdeo D. Mandal
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摘要

在当前形势下,日益严重的水污染对人类和动物都构成了严重威胁。低成本的光学材料,尤其是光催化材料,对于改善现状,满足全球能源需求,同时减少对环境的破坏,具有极其重要的意义。本研究旨在开发低成本、低温可重复的方法,合成适合在可见光照射下降解一种非常危险的水污染染料的多功能材料。本研究采用半湿化学方法合成了一种多功能 Bi12GeO20 化合物,该化合物具有光催化活性,可在可见光照射下降解罗丹明 B(RhB)染料。利用低温化学工艺成功制备了具有多晶结构的 Bi12GeO20(BGO)陶瓷。X 射线粉末衍射揭示了单相 BGO 陶瓷的形成。经过稳定化、X 射线衍射和 TEM 扫描的纳米级 BGO 陶瓷颗粒的粒径在 60-10 纳米之间。由于 Bi12GeO20 具有良好的带隙(2.72eV)和矽线石型,因此在可见光照射下具有很强的光催化降解罗丹明 B(RhB)染料的活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studies of multifunctional Bi12GeO20 compound synthesized by chemical route
Increasing water pollution poses a serious threat to both humankind and animals in the current situation. Low cost optical especially photocatalytic material is of utmost relevance to improve situation and meet the global energy demand with little environmental damage. The aim of this study is to develop low-cost low temperature reproducible method to synthesize multifunctional material suitable for degradation of a very dangerous water contaminant dye under visible light exposure. A semiwet chemical route was used to synthesize a multifunctional Bi12GeO20 compound suitable for photocatalytic activity for the degradation of Rhodamine B (RhB) dye under visible light exposure. Bi12GeO20 (BGO) ceramic with polycrystalline structure was prepared successfully e using a low temperature chemical process. X-ray powder diffraction reveals that single-phase BGO ceramic was formed. Nanosized BGO ceramic particles that had been stabilized, XRD and TEM to showed particle sizes in the 60–10 nm range. Due to the favorable band gap (2.72 eV) and the sillenite type Bi12GeO20 exhibits strong photocatalytic activity for the degradation of Rhodamine B (RhB) dye under visible light exposure.
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