M. Valle-Sánchez, Osvaldo F. López-Saladino, N. González-Rivas, Y. Estévez-Martínez, Bernardo A. Frontana-Uribe, Erick Cuevas-Yáñez
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At the Speed of Light: Recent Advances on Photocatalyzed Generation and Applications of Iminyl Radicals Promoted by Visible-light
Nitrogen-positioned radicals are chemical entities that have a lengthier history than carbon ones and
their high reactivity makes them invaluable. But, despite its power, much of its chemistry is still uncharted.
Currently, developed methodologies to access nitrogen-positioned radicals, such as transition metal catalysis or
visible-light photoredox methods through a single-electron transfer process, avoiding the use of harmful or
toxic reagents, excess raw materials, solvents as well as pre-functionalization steps or extensive synthetic
routes are in continuous progress. This revision aims to depict the recent advances in the field of iminylradicals’
syntheses, a special class of radicals placed on nitrogen, catalyzed by transition metals or photoredox
techniques for the construction of C-N bonds and their synthetic applications. This work serves as a
comprehensive guide for the scope of synthetic applications that this kind of radicals could have.
期刊介绍:
Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.