研究添加碲对 Ti6Al4V 合金耐腐蚀性的影响

Haydar H. J. Jamal Al-Deen, Basmal H Abdul Amir
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摘要

本研究旨在探讨碲合金元素(0.5、1、1.5、2、2.5、3、3.5、4、4.5 和 5 wt%)对 Ti6Al4V 合金在 Hank 和唾液溶液中耐腐蚀性的影响。所有合金都是通过粉末冶金技术制备的,压制压力为 800MP,绿色样品在惰性气体(氩气)中先在 350 C0 下烧结 1 小时,然后在 550 C0 下烧结 1 小时,再在 1000 C0 下烧结 2 小时,然后样品在炉中冷却至室温。使用光学显微镜观察了微观结构,结果表明所有合金试样都包含两个区域:α-钛相和β-钛相。一般来说,与基合金相比,由于 Te 作为 α 稳定剂元素的作用,Te 元素的添加会导致 α 相的增加。在汉克溶液和唾液溶液中进行的电化学测试(电位极化和 OCP - 时间测量)用于评估 Ti6Al4V 合金的耐腐蚀性。加入碲后,OCP 向正方向移动。这使合金变得更加惰性,并通过降低腐蚀电流密度来提高其耐腐蚀性。唾液溶液中的改善百分比从 2.50% 到 61.92%,汉克溶液中的改善百分比从 16.27% 到 88.32%。两种溶液的最佳改进百分比均为 5%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation The Effect of Tellurium Addition on Corrosion Resistance of Ti6Al4V alloy
The purpose of this study is to investigate the impact of Tellurium alloying element (0.5, 1, 1.5 ,2 ,2.5 ,3,3.5 ,4 ,4.5 and 5 wt%) on corrosion resistance of Ti6Al4V alloy in Hank and saliva solutions. All alloys have been prepared by powder metallurgy technique, the compact pressure was determined as 800MP and the green samples sintered at 350 C0 for 1h then at 550 C0 for 1h and at 1000 C0 for 2 h in inert gas (of Argon), then the samples cooled in the furnace to room temperature. The microstructure was observed using a light optical microscope and has shown that all specimens of alloys contain two regions: the α-Ti phase and the β-Ti phase. Generally, compared with the base alloy, the addition of the Te element leads to an increase in the α-phase due to the effect of Te as the α stabilizer element. Electrochemical tests (potentiodynamic polarization and OCP – Time measurement) in Hank's and saliva solutions were used to evaluate corrosion resistance of Ti6Al4V alloy. When tellurium was added, the OCP shifted to the positive direction. This makes the alloy more noble and increases its resistance to corrosion by decreasing corrosion current density. The percentage of improvement ranges from 2.50% to 61.92% in saliva solution and from 16.27% to 88.32% in Hank's solution. For both solutions, the best percentage of improvement is 5% Te.
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