新型神奇材料--令人振奋的技术前景

Akm Azharul Islam
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引用次数: 0

摘要

从母体三维 MAX 相中蚀刻出的二维 MXene 纳米材料在材料科学领域取得了重大进展。通式为 Mn+1AXn (n=1,2,3,4......)的层状三元碳化物、氮化物和硼化物化合物构成了三维 MAX 相材料,其中 A 是 IIA 族或 IIIA 族元素,M 是早期过渡金属,X 是 C、N 或 B。MAX 材料具有一系列与金属和陶瓷相似的特性。它们有助于开发高效发动机、可承受损坏的热系统、抗疲劳性增强和高温刚性保持技术。二维 MXenes 有可能被称为纳米材料中的 "神奇材料"。由于其原子级的超薄尺寸所带来的奇妙机械特性,以及不同寻常的电学和光学特性,它们已成为近年来材料研究的焦点。这些纳米材料是与多层石墨烯相当的多层导电材料。研究发现,它们可用于多种应用,如储能材料、复合材料加固、化学、环境和生物传感器以及电子设备。最近,纳米材料在光电子学、场效应晶体管、透明导电电极、电磁干扰屏蔽、能量存储和其他领域的应用取得了长足的进步。最近一项关于 Ti3C2 MXene 的研究揭示了纳米材料作为新型陶瓷光热剂用于癌症治疗的潜力。同样的二维纳米材料也可用于海水淡化和净化膜,因为它具有抗菌和抗生物污垢的特性。基于 MXene 的压阻传感器还能检测微弱的压力和人类轻微的弯曲释放动作。它可用于恢复行走或打字时肌肉收缩所损失的摩擦能量。由于 MAX 相是 MXenes 的前体,前者的价值在于人们对后者的兴趣与日俱增。本综述概述了从开创性的 MXene 出版至今的文献,包括作者本人的工作。它提供了有关新奇材料以及 MAX 相的特性、合成、晶体结构、当前和未来用途的信息。J. Bangladesh Acad:2024 年 6 月
本文章由计算机程序翻译,如有差异,请以英文原文为准。
New wonder materials - exciting technological horizon
A significant advancement in materials science has been made with the 2D MXene nanomaterials that were etched from their parent 3D MAX phases. Layered ternary carbide, nitride, and boride compounds with the general formula Mn+1AXn (n=1,2, 3,4 ...) make up the 3D MAX phase materials, where A is an element of Group IIA or IIIA, M is an early transition metal, and X is either C, N, or B. MXene's chemical formula is Mn+1Xn, whereas that of the precursor is Mn+1AXn. The MAX materials have a distinct set of properties that are similar to those of metal and ceramic. They are helpful in the development of high-efficiency engines, thermal systems that can withstand damage, fatigue resistance enhancement, and high-temperature rigidity retention technologies. The 2D MXenes are potentially described as a „wonder material‟ in the class of nanomaterials. Because of their intriguing mechanical properties resulting from their atomically thin dimensions, as well as their unusual electrical and optical properties, these have become the focus of materials research in recent years. These nanomaterials are multilayer electrically conductive materials that are comparable to multilayer graphene. They have been discovered to be beneficial for a variety of applications, such as energy storage materials, composite reinforcement, chemical, environmental, and biological sensors, and electronic devices. The recent advancements in the use of nanomaterials in optoelectronics, field-effect transistors, transparent conductive electrodes and shielding against electromagnetic interference, energy storage, and other fields have been extensively documented. The potential of nanomaterials as a novel ceramic photothermal agent employed in cancer therapy has been revealed by a very recent study on Ti3C2 MXene. The same 2D nanomaterial can be used in water desalination and purification membranes since it has antibacterial qualities and is resistant to bio fouling. The MXene-based piezoresistive sensor is also capable of detecting weak pressures and the slight bending-release actions of humans. It can be applied to recover lost frictional energy from, say, walking or typing-related muscular contractions. Since MAX phases are precursors to MXenes, the former are valuable due to the growing interest in the latter. This review provides an overview of the literature, including the author's own work, from the groundbreaking MXene publication to the present. It provides information on the characteristics, synthesis, crystal structure, and current and future uses of the new wonder materials as well as the MAX phases. J. Bangladesh Acad. Sci. 48(1); 1-25: June 2024
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