V. KOZLOV V, R. SHOLIDODOV M, K. ALTUNINA L, A. KUVSHINOV V, A. STASYEVA L, R. SAIDENTSAL A
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引用次数: 0
摘要
根据对深层共晶溶剂(DES)甘油-碳酰胺-硼酸三元体系中相平衡的研究结果,开发了一种物理化学参数可在较大范围内调节的组合物。研究了这种组合物对提高石油采收率的影响,并介绍了基于 DES 的组合物对乌申斯克油田碳酸盐岩储层中异质地层过滤特性影响的实验室研究结果。通过物理建模评估了组合物对处于开发早期和晚期阶段的油田的效率。使用该成分处理异质储层模型,由于过滤流量均衡、储层覆盖率增加和初始渗透率恢复,在低温或高温条件下均可大幅提高石油置换系数。对使用该组合物处理前后的高粘度重油成分和性质的调查表明,使用基于 DES 的酸组合物不会影响油的质量成分。组合物的使用主要导致低分子结构和高分子结构含量的重新分配:主要是轻质闭塞碳氢化合物被取代,而重油成分被吸附在储层上。
ACID COMPOSITION BASED ON DEEP EUTECTIC SOLVENTS FOR DISPLACING HEAVY OIL
A composition characterised by adjustable physicochemical parameters within a broad range has been developed relying on the results of studies of the phase equilibria in the ternary system of deep eutectic solvents (DES) glycerol - carbamide - boric acid. The effect of this composition on oil recovery enhancement is studied, and results obtained in the laboratory studies of the effect of DES-based composition on the filtration characteristics of a heterogeneous formation in the carbonate reservoir of the Usinsk field are presented. The efficiency of the composition for oilfields at the early and late stages of development has been assessed by physical modelling. The treatment of a model of a heterogeneous reservoir with the composition is determined to cause a substantial increase in oil displacement coefficient at either low or high temperatures due to equalisation of filtration flows, an increase in reservoir coverage, and restoration of initial permeability. Investigation of the composition and properties of heavy high-viscosity oil before and after treatment with the composition shows that the application of DES-based acid composition does not affect the qualitative composition of oil. The use of the composition leads mainly to redistribution of the content of low- and high-molecular structures: predominantly light occluded hydrocarbons are displaced, while heavy oil components are adsorbed on the reservoir.