Jing Huang , Dawei Yi , Jingbo Yan , Bin Han , Yihang He , Zhen Yang , Yongli Zhou , Fang Yang
{"title":"添加锰对高温蒸汽环境下耐热钢氧化性能的影响","authors":"Jing Huang , Dawei Yi , Jingbo Yan , Bin Han , Yihang He , Zhen Yang , Yongli Zhou , Fang Yang","doi":"10.1016/j.corcom.2023.09.003","DOIUrl":null,"url":null,"abstract":"<div><p>A comparative study of high chromium (Super304H) and high manganese low chromium heat-resistant steel (HT630) was carried out at 650 °C in steam. Results indicate that the high manganese content in HT630 significantly improved its oxidation resistance. It is ascribed to the formation of a dense protective MnCr<sub>2</sub>O<sub>4</sub> oxide layer during oxidation. MnCr<sub>2</sub>O<sub>4</sub> layer effectively inhibits the diffusion of iron, suppresses the growth of iron-rich oxides, promotes the formation of an iron-rich protective interface with the matrix, and improves the overall oxidation resistance.</p></div>","PeriodicalId":100337,"journal":{"name":"Corrosion Communications","volume":"14 ","pages":"Pages 72-84"},"PeriodicalIF":0.0000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667266924000239/pdfft?md5=81ef0128df487f46f42d3255a4bf0699&pid=1-s2.0-S2667266924000239-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Effects of Mn addition on oxidation behaviour of heat-resistant steel in a high-temperature steam environment\",\"authors\":\"Jing Huang , Dawei Yi , Jingbo Yan , Bin Han , Yihang He , Zhen Yang , Yongli Zhou , Fang Yang\",\"doi\":\"10.1016/j.corcom.2023.09.003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A comparative study of high chromium (Super304H) and high manganese low chromium heat-resistant steel (HT630) was carried out at 650 °C in steam. Results indicate that the high manganese content in HT630 significantly improved its oxidation resistance. It is ascribed to the formation of a dense protective MnCr<sub>2</sub>O<sub>4</sub> oxide layer during oxidation. MnCr<sub>2</sub>O<sub>4</sub> layer effectively inhibits the diffusion of iron, suppresses the growth of iron-rich oxides, promotes the formation of an iron-rich protective interface with the matrix, and improves the overall oxidation resistance.</p></div>\",\"PeriodicalId\":100337,\"journal\":{\"name\":\"Corrosion Communications\",\"volume\":\"14 \",\"pages\":\"Pages 72-84\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667266924000239/pdfft?md5=81ef0128df487f46f42d3255a4bf0699&pid=1-s2.0-S2667266924000239-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667266924000239\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667266924000239","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
在 650 °C 蒸汽中对高铬(Super304H)和高锰低铬耐热钢(HT630)进行了比较研究。结果表明,HT630 中的高锰含量显著提高了其抗氧化性。这是因为在氧化过程中形成了致密的 MnCr2O4 氧化物保护层。MnCr2O4 层能有效抑制铁的扩散,抑制富铁氧化物的生长,促进与基体形成富铁保护界面,提高整体抗氧化性。
Effects of Mn addition on oxidation behaviour of heat-resistant steel in a high-temperature steam environment
A comparative study of high chromium (Super304H) and high manganese low chromium heat-resistant steel (HT630) was carried out at 650 °C in steam. Results indicate that the high manganese content in HT630 significantly improved its oxidation resistance. It is ascribed to the formation of a dense protective MnCr2O4 oxide layer during oxidation. MnCr2O4 layer effectively inhibits the diffusion of iron, suppresses the growth of iron-rich oxides, promotes the formation of an iron-rich protective interface with the matrix, and improves the overall oxidation resistance.