{"title":"一种具有吸附特性和 Hirshfeld 表面分析的锌(II)基一维配位聚合物","authors":"Safarov Azamat Rasulovich, Ibragimov Aziz Bakhtiyarovich, Ruzmetov Abror Khamidjanovich, Normamatov Adkhamjon Sadullayevich, Yakubov Yuldosh Yusupboyevich, Abdullaev Ahrorjon Khabibjonovich, Adizov Bobirjon Zamirovich, Eshmetov Izzat Dosimbatovich, Muhammad Nadeem Akhtar, Ibragimov Avazbek Bakhtiyarovich, Ashurov Jamshid Mengnorovich","doi":"10.1007/s11224-024-02340-2","DOIUrl":null,"url":null,"abstract":"<div><p>A polymeric coordination compound [Zn<sub>2(</sub>PABA)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>Cl<sub>2</sub>]<sub>n</sub> (<b>1</b>) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We examined and explicated the porosity of the compound and employed a low-temperature nitrogen adsorption technique at 77 kelvins. Throughout the experiments, the nitrogen partial pressure ranged from 0.005 to 0.995 P/P<sup>0</sup>, aligning with the nitrogen adsorption and desorption curves. The surface area (SBET) was found to be 1945.72 m<sup>2</sup>/g with a micropore area of 361.56 m<sup>2</sup>/g that ensures the material’s ability to effectively adsorb small molecules. The nitrogen adsorption behavior on this compound is not only facilitates a deeper comprehension of its textural and structural attributes but also unveils potential applications, especially in pharmaceutical domains. Additionally, Hirschfeld surface analysis was performed, yielding interatomic interaction percentages on the Hirschfeld surface.</p></div>","PeriodicalId":780,"journal":{"name":"Structural Chemistry","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Zn(II)-based 1D Coordination Polymer with Adsorption Properties and Hirshfeld Surface Analysis\",\"authors\":\"Safarov Azamat Rasulovich, Ibragimov Aziz Bakhtiyarovich, Ruzmetov Abror Khamidjanovich, Normamatov Adkhamjon Sadullayevich, Yakubov Yuldosh Yusupboyevich, Abdullaev Ahrorjon Khabibjonovich, Adizov Bobirjon Zamirovich, Eshmetov Izzat Dosimbatovich, Muhammad Nadeem Akhtar, Ibragimov Avazbek Bakhtiyarovich, Ashurov Jamshid Mengnorovich\",\"doi\":\"10.1007/s11224-024-02340-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A polymeric coordination compound [Zn<sub>2(</sub>PABA)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>Cl<sub>2</sub>]<sub>n</sub> (<b>1</b>) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We examined and explicated the porosity of the compound and employed a low-temperature nitrogen adsorption technique at 77 kelvins. Throughout the experiments, the nitrogen partial pressure ranged from 0.005 to 0.995 P/P<sup>0</sup>, aligning with the nitrogen adsorption and desorption curves. The surface area (SBET) was found to be 1945.72 m<sup>2</sup>/g with a micropore area of 361.56 m<sup>2</sup>/g that ensures the material’s ability to effectively adsorb small molecules. The nitrogen adsorption behavior on this compound is not only facilitates a deeper comprehension of its textural and structural attributes but also unveils potential applications, especially in pharmaceutical domains. Additionally, Hirschfeld surface analysis was performed, yielding interatomic interaction percentages on the Hirschfeld surface.</p></div>\",\"PeriodicalId\":780,\"journal\":{\"name\":\"Structural Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-06-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11224-024-02340-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11224-024-02340-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Zn(II)-based 1D Coordination Polymer with Adsorption Properties and Hirshfeld Surface Analysis
A polymeric coordination compound [Zn2(PABA)2(H2O)2Cl2]n (1) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We examined and explicated the porosity of the compound and employed a low-temperature nitrogen adsorption technique at 77 kelvins. Throughout the experiments, the nitrogen partial pressure ranged from 0.005 to 0.995 P/P0, aligning with the nitrogen adsorption and desorption curves. The surface area (SBET) was found to be 1945.72 m2/g with a micropore area of 361.56 m2/g that ensures the material’s ability to effectively adsorb small molecules. The nitrogen adsorption behavior on this compound is not only facilitates a deeper comprehension of its textural and structural attributes but also unveils potential applications, especially in pharmaceutical domains. Additionally, Hirschfeld surface analysis was performed, yielding interatomic interaction percentages on the Hirschfeld surface.
期刊介绍：
Structural Chemistry is an international forum for the publication of peer-reviewed original research papers that cover the condensed and gaseous states of matter and involve numerous techniques for the determination of structure and energetics, their results, and the conclusions derived from these studies. The journal overcomes the unnatural separation in the current literature among the areas of structure determination, energetics, and applications, as well as builds a bridge to other chemical disciplines. Ist comprehensive coverage encompasses broad discussion of results, observation of relationships among various properties, and the description and application of structure and energy information in all domains of chemistry.
We welcome the broadest range of accounts of research in structural chemistry involving the discussion of methodologies and structures,experimental, theoretical, and computational, and their combinations. We encourage discussions of structural information collected for their chemicaland biological significance.
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