插入两个噻吩间隔物的 1,3-二硫代[6]树枝烯类似物的合成及其特性

IF 1.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Letters Pub Date : 2024-05-30 DOI:10.1093/chemle/upae104

Tomoya Misaki, Masataka Nishiwaki, Toshiki Ito, Masafumi Ueda, Masahiro Fujisaki, Aya Yoshimura, Takashi Shirahata, Minoru Hayashi, Yohji Misaki

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引用次数: 0

摘要

我们成功合成了插入两个噻吩间隔的 1,3-二硫代[6]树枝烯类似物（2）的衍生物。循环伏安法和光谱电化学法显示，根据正电荷的分布，它们的氧化还原行为因取代基在 1,3-二硫环上的位置和电子效应而异。

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Synthesis and Properties of 1,3-Dithiole[6]dendralene Analogs with Two Thiophene Spacers Inserted

Derivatives of a 1,3-dithiole[6]dendralene analog with two thiophene spacers inserted (2) have been successfully synthesized. Cyclic voltammetry and spectroelectrochemistry revealed that their redox behavior, based on the distribution of the positive charges, differed depending on the position and the electronic effect of substituents on the 1,3-dithiole rings.

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来源期刊

Chemistry Letters 化学-化学综合

CiteScore

3.00

自引率

6.20%

发文量

260

审稿时长

1.2 months

期刊介绍： Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry