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2-羰基取代的 1H-苯并[f]色烯与氰基乙酸的 N-芳基酰胺的反应

IF 1.4 4区 化学 Q3 CHEMISTRY, ORGANIC
Chemistry of Heterocyclic Compounds Pub Date : 2024-06-04 DOI:10.1007/s10593-024-03312-4
Dmitry V. Osipov, Pavel E. Krasnikov, Alina A. Artemenko
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引用次数: 0

摘要

通过 2-三氟乙酰基-1H-苯并[f]色烯与氰基乙酸的 N-芳基酰胺的反应，合成了一系列 2-氧代-6-三氟甲基吡啶-3-甲酰胺，它们是羧基迈克尔反应、索普-齐格勒环化反应和迪姆洛特重排反应的级联产物。在 1H-苯并[f]色烯-2-甲醛的情况下，分离出了相应的 Knoevenagel 加合物。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

A reaction of 2-carbonyl-substituted 1H-benzo[f]chromenes with N-arylamides of cyanoacetic acid

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A reaction of 2-carbonyl-substituted 1H-benzo[f]chromenes with N-arylamides of cyanoacetic acid

A reaction of 2-trifluoroacetyl-1H-benzo[f]chromenes with N-arylamides of cyanoacetic acid led to the synthesis of a series of 2-oxo-6-trifluoromethylpyridine-3-carboxamides as products of a cascade of the carbo-Michael reaction, Thorpe–Ziegler cyclization, and Dimroth rearrangement. In the case of 1H-benzo[f]chromene-2-carbaldehydes, the corresponding Knoevenagel adducts were isolated.

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来源期刊
Chemistry of Heterocyclic Compounds
Chemistry of Heterocyclic Compounds 化学-有机化学
CiteScore
2.90
自引率
13.30%
发文量
98
审稿时长
1 months
期刊介绍： The international journal Chemistry of Heterocyclic Compounds publishes original papers, short communications, reviews, and mini-reviews dealing with problems in the field of heterocyclic chemistry in Russian and English. The Journal also publishes reviews and annotations on new books and brief reports on conferences in the field of heterocyclic chemistry, as well as commemo­ra­tives dedicated to prominent heterocyclic chemists.
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