Aqilah A. Hakami, Hajar S. Alorfi, Thoraya A. Farghaly, Mahmoud A. Hussein
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The results of the X-ray diffraction patterns indicate that the multi-wall carbon nanotubes are really in the polymer matrix. The thermal analysis of these polymer nanocomposites shows high thermal stability. The agar diffusion technique was used to assess the antibacterial properties of the freshly synthesized polymer nanocomposites against various bacterial and fungal species. The chosen bacteria and fungi were susceptible to varying degrees of antimicrobial and antifungal activity in the polymer nanocomposites that were evaluated. Moreover, the antibacterial properties of the fabricated Polymer nanocomposites were assessed through colony forming units against Escherichia coli bacteria and showed good effectiveness of all tested polymer nanocomposites. All samples showed an effect on bacterial growth after 12 h by 22%–35%. 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引用次数: 0
摘要
最近,一种新型的生物活性聚合物纳米复合材料系列通过缩聚法和超声波辐射被制造出来。这些纳米复合材料由多壁碳纳米管和聚氮化合物组成,聚氮化合物是基于吡唑分子的各种衍生物。聚氮亚胺聚合物中添加了 2% 浓度的多壁碳纳米管。生产出的聚合物纳米复合材料通过傅立叶变换红外光谱进行鉴定,并通过 X 射线衍射、扫描电子显微镜和透射电子显微镜等常用表征工具进行表征。热重分析和差热重力法测量了热稳定性。X 射线衍射图样的结果表明,多壁碳纳米管确实存在于聚合物基体中。这些聚合物纳米复合材料的热分析表明具有很高的热稳定性。琼脂扩散技术用于评估新合成的聚合物纳米复合材料对各种细菌和真菌的抗菌性能。所选细菌和真菌对所评估的聚合物纳米复合材料具有不同程度的抗菌和抗真菌活性。此外,通过对大肠杆菌的菌落形成单位来评估所制备的聚合物纳米复合材料的抗菌性能,结果表明所有测试的聚合物纳米复合材料都具有良好的抗菌效果。12 小时后,所有样品对细菌生长的抑制率均为 22%-35%。24 小时后,制备的聚合物纳米复合材料对大肠杆菌的抑制率最高,达到 45%-60%。
Synthesis, and antimicrobial activity of polyazomethine-pyrazole/multi-walled carbon nanotubes nanocomposite materials
A novel series of bioactive polymer nanocomposites was recently created using the polycondensation method in conjunction with ultrasonic radiation. These nanocomposites comprise multi-wall carbon nanotubes and polyazomethine, which is based on the pyrazole moiety with various derivatives. The polyazomethine polymer was supplemented with a 2% concentration of multi-wall carbon nanotubes. The produced polymer nanocomposites were identified by Fourier-transform infrared spectroscopy and characterized by common characterization tools including X-ray diffraction, Scanning electron microscopy, and Transmission electron microscopy. The thermal stability was measured by thermogravimetric analysis and differential thermal gravimetry. The results of the X-ray diffraction patterns indicate that the multi-wall carbon nanotubes are really in the polymer matrix. The thermal analysis of these polymer nanocomposites shows high thermal stability. The agar diffusion technique was used to assess the antibacterial properties of the freshly synthesized polymer nanocomposites against various bacterial and fungal species. The chosen bacteria and fungi were susceptible to varying degrees of antimicrobial and antifungal activity in the polymer nanocomposites that were evaluated. Moreover, the antibacterial properties of the fabricated Polymer nanocomposites were assessed through colony forming units against Escherichia coli bacteria and showed good effectiveness of all tested polymer nanocomposites. All samples showed an effect on bacterial growth after 12 h by 22%–35%. After 24 h, the percent inhibition of E. coli in the presence of the prepared polymer nanocomposites was highest; it showed 45%–60%.