A. G. Chetverikova, V. L. Berdinsky, O. N. Kanygina, E. K. Alidzhanov, H. N. Nikiyan
{"title":"将杂质离子 Mn2+ 和 Fe3+ 作为配对自旋标签，利用 ESR 方法研究叶硅酸盐的结构转变","authors":"A. G. Chetverikova, V. L. Berdinsky, O. N. Kanygina, E. K. Alidzhanov, H. N. Nikiyan","doi":"10.1134/S1990793124020052","DOIUrl":null,"url":null,"abstract":"<p>Impurity paramagnetic ions Mn<sup>2+</sup> and high spin Fe<sup>3+</sup> (<i>S</i> = 5/2) are shown to be very informative paired spin labels to investigate structural transformations in natural aluminosilicate clay minerals by ESR spectroscopy. Second derivative ESR (SD ESR) enables to detect minor narrow lines of the ions against the background of intense broad lines of other paramagnetic impurities. Complex SD ESR spectra of the ions are explained by the Jahn-Teller effect and hyperfine interactions with OH-groups. SD ESR spectra before and after heating (620 and 900°C) proved transformations of octahedral crystal cells accompanied by the loss of the OH-groups, displacement of the ions to equivalent positions.</p>","PeriodicalId":768,"journal":{"name":"Russian Journal of Physical Chemistry B","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impurity Ions Mn2+ and Fe3+ as Paired Spin Labels for the Study of Structural Transformations in Phyllosilicates by the ESR Method\",\"authors\":\"A. G. Chetverikova, V. L. Berdinsky, O. N. Kanygina, E. K. Alidzhanov, H. N. Nikiyan\",\"doi\":\"10.1134/S1990793124020052\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Impurity paramagnetic ions Mn<sup>2+</sup> and high spin Fe<sup>3+</sup> (<i>S</i> = 5/2) are shown to be very informative paired spin labels to investigate structural transformations in natural aluminosilicate clay minerals by ESR spectroscopy. Second derivative ESR (SD ESR) enables to detect minor narrow lines of the ions against the background of intense broad lines of other paramagnetic impurities. Complex SD ESR spectra of the ions are explained by the Jahn-Teller effect and hyperfine interactions with OH-groups. SD ESR spectra before and after heating (620 and 900°C) proved transformations of octahedral crystal cells accompanied by the loss of the OH-groups, displacement of the ions to equivalent positions.</p>\",\"PeriodicalId\":768,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry B\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1990793124020052\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry B","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1990793124020052","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
Impurity Ions Mn2+ and Fe3+ as Paired Spin Labels for the Study of Structural Transformations in Phyllosilicates by the ESR Method
Impurity paramagnetic ions Mn2+ and high spin Fe3+ (S = 5/2) are shown to be very informative paired spin labels to investigate structural transformations in natural aluminosilicate clay minerals by ESR spectroscopy. Second derivative ESR (SD ESR) enables to detect minor narrow lines of the ions against the background of intense broad lines of other paramagnetic impurities. Complex SD ESR spectra of the ions are explained by the Jahn-Teller effect and hyperfine interactions with OH-groups. SD ESR spectra before and after heating (620 and 900°C) proved transformations of octahedral crystal cells accompanied by the loss of the OH-groups, displacement of the ions to equivalent positions.
期刊介绍：
Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
