以玻璃化转变温度为特征的无定形水溶性碳水化合物的水吸附等温线和临界水活性。

IF 1.2 Q4 BIOCHEMISTRY & MOLECULAR BIOLOGY
Journal of applied glycoscience Pub Date : 2024-04-20 eCollection Date: 2024-01-01 DOI:10.5458/jag.jag.JAG-2023_0015
Yuichi Kashiwakura, Tomochika Sogabe, Sukritta Anantawittayanon, Takumi Mochizuki, Kiyoshi Kawai
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引用次数: 0

摘要

水溶性碳水化合物通常以无定形状态存在于食品中,并在玻璃转化温度(Tg)下发生玻璃-橡胶转化(玻璃转化)。临界含水量(Wc)和临界水活度(awc)分别是指在 298 K(典型环境温度)时发生玻璃化转变的含水量和水活度(aw)。对于无定形水溶性碳水化合物来说,Wc 可通过无水固体的 Tg(Tgs)使用以前报告过的公式进行预测。然而,目前仍缺乏预测 awc 的方法。本研究旨在建立一种基于 Tgs 的无定形水溶性碳水化合物 awc 预测方法。首先,研究了四种氢化淀粉水解物的水吸附等温线,并使用 Guggenheim-Anderson-de Boer(GAB)模型对结果进行了分析。其次,利用之前文献中报道的 Tgs 值评估了 Tgs 对 GAB 参数(C、K 和 Wm)的影响。随着 1/Tgs 的增加,C 和 Wm 分别呈对数下降和上升趋势。K 被固定为 1(常数),因为它几乎没有变化。这些结果使我们能够根据 Tgs 预测 GAB 参数。然后,GAB 模型可以根据 Wc 预测 awc,而 awc 是通过之前建立的方程确定的。预测的 awc 值与实验测定的 awc 值非常吻合。此外,我们还证明了这种 awc 预测方法也适用于无定形水溶性电解质和部分不溶于水的碳水化合物。因此,这种方法可用于无定形水溶性碳水化合物和以碳水化合物为基础的食品的质量控制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Water Sorption Isotherm and Critical Water Activity of Amorphous Water-Soluble Carbohydrates Characterized by the Glass Transition Temperature.

Water-soluble carbohydrates commonly exist in an amorphous state in foods and undergo glass-rubber transition (glass transition) at the glass transition temperature (Tg). The critical water content (Wc) and critical water activity (awc) are the water content and water activity (aw) at which the glass transition occurs at 298 K (typical ambient temperature), respectively. For amorphous water-soluble carbohydrates, Wc can be predicted from the Tg of anhydrous solid (Tgs) using previously reported equations. However, an approach for predicting awc is still lacking. This study aimed to establish an awc-predictive approach for amorphous water-soluble carbohydrates based on Tgs. First, the water sorption isotherms of four hydrogenated starch hydrolysates were investigated, and the results were analyzed using the Guggenheim-Anderson-de Boer (GAB) model. Second, the effect of Tgs on the GAB parameters (C, K, and Wm) was evaluated using the Tgs values reported in previous literatures. C and Wm decreased and increased logarithmically, respectively, with increasing 1/Tgs. K was fixed to 1 (constant), as it showed little variation. These results enabled the prediction of the GAB parameters from Tgs. The GAB model could then predict awc from Wc, which was determined using the previously established equations. The predicted awc values were in good agreement with the experimentally determined awc. Additionally, we demonstrated that this awc-prediction approach is also applicable to amorphous water-soluble electrolytes and partially water-insoluble carbohydrates. Thus, this approach can be used for the quality control of amorphous water-soluble carbohydrates and carbohydrate-based foods.

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来源期刊
Journal of applied glycoscience
Journal of applied glycoscience BIOCHEMISTRY & MOLECULAR BIOLOGY-
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