受人类影响的以河流为主的海洋边缘沉积有机碳命运的分子和放射性碳制约因素

IF 2.6 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY
Chenglong Wang , Chuchu Zhang , Zhuoyue Zhang , Qihang Liao , Yang Zhang , Ning Wang , Yaping Wang , Xinqing Zou
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引用次数: 0

摘要

有机碳(OC)埋藏在以河流为主的海洋边缘地区,在全球碳循环中发挥着关键作用,长期影响着大气中的二氧化碳水平。尽管其意义重大,但外部环境因素和内在特性对沉积 OC 的影响仍存在不确定性。在本研究中,我们对东海表层沉积物进行了全面分析,考察了地球化学性质(包括总 OC 含量 [TOC]、Δ14C、Δ13C 和 C/N 比值)、陆地生物标志物(正烷烃)和矿物性质(如比表面积、铝/硅比和矿物组成)。表层沉积物的Δ14C值显示出显著的空间异质性,划分出四个不同的子区域。Δ14C值与细粒沉积物、比表面积和粘土矿物之间存在很强的正相关性(均为p <0.01),表明矿物保护在影响沉积OC命运方面可能起着关键作用。陆相 OC 的比例向南逐渐降低,而海洋 OC 的比例则逐渐升高,与 Δ14C 的富集相对应。Δ14C值、矿物性质和OC来源比例的共同变化表明,陆相OC在向南迁移的过程中可能逐渐被海相OC所取代。Δ14C值的时间变化表明,海床侵蚀导致沿岸泥带的Δ14C值显著增加(p < 0.01),由于人类世期间新的沉积物循环,这种现象可能在全球以河流为主的海洋边缘地区普遍存在。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Molecular and radiocarbon constraints on the fate of sedimentary organic carbon in a human-impacted river-dominated ocean margin

Organic carbon (OC) burial in river-dominated ocean margins plays a pivotal role in the global carbon cycle, impacting atmospheric CO2 levels over the long term. Despite its significance, uncertainties persist regarding the influence of external environmental factors and intrinsic properties on sedimentary OC. In this study, we conducted a comprehensive analysis of surface sediments from the East China Sea, examining geochemical properties (including total OC content [TOC], Δ14C, δ13C, and C/N ratio), terrestrial biomarkers (n-alkanes), and mineral properties (such as specific surface area, Al/Si ratio, and mineral composition). Our aim was to shed light on the fate of sedimentary OC.

The surface sediment's Δ14C values displayed significant spatial heterogeneity, delineating four distinct sub-regions. Strong positive correlations (all p < 0.01) were found between the ∆14C values and fine-grained sediments, specific surface area, and clay minerals, suggesting the potentially pivotal role of mineral protection in shaping the fate of sedimentary OC. The proportion of terrestrial OC gradually decreased towards the south, while marine OC proportion increased, corresponding to the enrichment of Δ14C. The co-variation of Δ14C values, mineral properties, and OC source proportions suggests that terrestrial OC may undergo progressive replacement by marine OC during southward transport. Temporal variations in ∆14C values indicated that seabed erosion led to a significant increase in ∆14C values (p < 0.01) in the coastal mud belt, a phenomenon likely common in river-dominated ocean margins globally due to the new sediment cycle during the Anthropocene.

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来源期刊
Marine Geology
Marine Geology 地学-地球科学综合
CiteScore
6.10
自引率
6.90%
发文量
175
审稿时长
21.9 weeks
期刊介绍: Marine Geology is the premier international journal on marine geological processes in the broadest sense. We seek papers that are comprehensive, interdisciplinary and synthetic that will be lasting contributions to the field. Although most papers are based on regional studies, they must demonstrate new findings of international significance. We accept papers on subjects as diverse as seafloor hydrothermal systems, beach dynamics, early diagenesis, microbiological studies in sediments, palaeoclimate studies and geophysical studies of the seabed. We encourage papers that address emerging new fields, for example the influence of anthropogenic processes on coastal/marine geology and coastal/marine geoarchaeology. We insist that the papers are concerned with the marine realm and that they deal with geology: with rocks, sediments, and physical and chemical processes affecting them. Papers should address scientific hypotheses: highly descriptive data compilations or papers that deal only with marine management and risk assessment should be submitted to other journals. Papers on laboratory or modelling studies must demonstrate direct relevance to marine processes or deposits. The primary criteria for acceptance of papers is that the science is of high quality, novel, significant, and of broad international interest.
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