Chenglong Wang , Chuchu Zhang , Zhuoyue Zhang , Qihang Liao , Yang Zhang , Ning Wang , Yaping Wang , Xinqing Zou
{"title":"受人类影响的以河流为主的海洋边缘沉积有机碳命运的分子和放射性碳制约因素","authors":"Chenglong Wang , Chuchu Zhang , Zhuoyue Zhang , Qihang Liao , Yang Zhang , Ning Wang , Yaping Wang , Xinqing Zou","doi":"10.1016/j.margeo.2024.107322","DOIUrl":null,"url":null,"abstract":"<div><p>Organic carbon (OC) burial in river-dominated ocean margins plays a pivotal role in the global carbon cycle, impacting atmospheric CO<sub>2</sub> levels over the long term. Despite its significance, uncertainties persist regarding the influence of external environmental factors and intrinsic properties on sedimentary OC. In this study, we conducted a comprehensive analysis of surface sediments from the East China Sea, examining geochemical properties (including total OC content [TOC], Δ<sup>14</sup>C, δ<sup>13</sup>C, and C/N ratio), terrestrial biomarkers (<em>n</em>-alkanes), and mineral properties (such as specific surface area, Al/Si ratio, and mineral composition). Our aim was to shed light on the fate of sedimentary OC.</p><p>The surface sediment's Δ<sup>14</sup>C values displayed significant spatial heterogeneity, delineating four distinct sub-regions. Strong positive correlations (all <em>p</em> < 0.01) were found between the ∆<sup>14</sup>C values and fine-grained sediments, specific surface area, and clay minerals, suggesting the potentially pivotal role of mineral protection in shaping the fate of sedimentary OC. The proportion of terrestrial OC gradually decreased towards the south, while marine OC proportion increased, corresponding to the enrichment of Δ<sup>14</sup>C. The co-variation of Δ<sup>14</sup>C values, mineral properties, and OC source proportions suggests that terrestrial OC may undergo progressive replacement by marine OC during southward transport. Temporal variations in ∆<sup>14</sup>C values indicated that seabed erosion led to a significant increase in ∆<sup>14</sup>C values (<em>p</em> < 0.01) in the coastal mud belt, a phenomenon likely common in river-dominated ocean margins globally due to the new sediment cycle during the Anthropocene.</p></div>","PeriodicalId":18229,"journal":{"name":"Marine Geology","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Molecular and radiocarbon constraints on the fate of sedimentary organic carbon in a human-impacted river-dominated ocean margin\",\"authors\":\"Chenglong Wang , Chuchu Zhang , Zhuoyue Zhang , Qihang Liao , Yang Zhang , Ning Wang , Yaping Wang , Xinqing Zou\",\"doi\":\"10.1016/j.margeo.2024.107322\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Organic carbon (OC) burial in river-dominated ocean margins plays a pivotal role in the global carbon cycle, impacting atmospheric CO<sub>2</sub> levels over the long term. Despite its significance, uncertainties persist regarding the influence of external environmental factors and intrinsic properties on sedimentary OC. In this study, we conducted a comprehensive analysis of surface sediments from the East China Sea, examining geochemical properties (including total OC content [TOC], Δ<sup>14</sup>C, δ<sup>13</sup>C, and C/N ratio), terrestrial biomarkers (<em>n</em>-alkanes), and mineral properties (such as specific surface area, Al/Si ratio, and mineral composition). Our aim was to shed light on the fate of sedimentary OC.</p><p>The surface sediment's Δ<sup>14</sup>C values displayed significant spatial heterogeneity, delineating four distinct sub-regions. Strong positive correlations (all <em>p</em> < 0.01) were found between the ∆<sup>14</sup>C values and fine-grained sediments, specific surface area, and clay minerals, suggesting the potentially pivotal role of mineral protection in shaping the fate of sedimentary OC. The proportion of terrestrial OC gradually decreased towards the south, while marine OC proportion increased, corresponding to the enrichment of Δ<sup>14</sup>C. The co-variation of Δ<sup>14</sup>C values, mineral properties, and OC source proportions suggests that terrestrial OC may undergo progressive replacement by marine OC during southward transport. Temporal variations in ∆<sup>14</sup>C values indicated that seabed erosion led to a significant increase in ∆<sup>14</sup>C values (<em>p</em> < 0.01) in the coastal mud belt, a phenomenon likely common in river-dominated ocean margins globally due to the new sediment cycle during the Anthropocene.</p></div>\",\"PeriodicalId\":18229,\"journal\":{\"name\":\"Marine Geology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Marine Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025322724001063\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Marine Geology","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025322724001063","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Molecular and radiocarbon constraints on the fate of sedimentary organic carbon in a human-impacted river-dominated ocean margin
Organic carbon (OC) burial in river-dominated ocean margins plays a pivotal role in the global carbon cycle, impacting atmospheric CO2 levels over the long term. Despite its significance, uncertainties persist regarding the influence of external environmental factors and intrinsic properties on sedimentary OC. In this study, we conducted a comprehensive analysis of surface sediments from the East China Sea, examining geochemical properties (including total OC content [TOC], Δ14C, δ13C, and C/N ratio), terrestrial biomarkers (n-alkanes), and mineral properties (such as specific surface area, Al/Si ratio, and mineral composition). Our aim was to shed light on the fate of sedimentary OC.
The surface sediment's Δ14C values displayed significant spatial heterogeneity, delineating four distinct sub-regions. Strong positive correlations (all p < 0.01) were found between the ∆14C values and fine-grained sediments, specific surface area, and clay minerals, suggesting the potentially pivotal role of mineral protection in shaping the fate of sedimentary OC. The proportion of terrestrial OC gradually decreased towards the south, while marine OC proportion increased, corresponding to the enrichment of Δ14C. The co-variation of Δ14C values, mineral properties, and OC source proportions suggests that terrestrial OC may undergo progressive replacement by marine OC during southward transport. Temporal variations in ∆14C values indicated that seabed erosion led to a significant increase in ∆14C values (p < 0.01) in the coastal mud belt, a phenomenon likely common in river-dominated ocean margins globally due to the new sediment cycle during the Anthropocene.
期刊介绍:
Marine Geology is the premier international journal on marine geological processes in the broadest sense. We seek papers that are comprehensive, interdisciplinary and synthetic that will be lasting contributions to the field. Although most papers are based on regional studies, they must demonstrate new findings of international significance. We accept papers on subjects as diverse as seafloor hydrothermal systems, beach dynamics, early diagenesis, microbiological studies in sediments, palaeoclimate studies and geophysical studies of the seabed. We encourage papers that address emerging new fields, for example the influence of anthropogenic processes on coastal/marine geology and coastal/marine geoarchaeology. We insist that the papers are concerned with the marine realm and that they deal with geology: with rocks, sediments, and physical and chemical processes affecting them. Papers should address scientific hypotheses: highly descriptive data compilations or papers that deal only with marine management and risk assessment should be submitted to other journals. Papers on laboratory or modelling studies must demonstrate direct relevance to marine processes or deposits. The primary criteria for acceptance of papers is that the science is of high quality, novel, significant, and of broad international interest.