Andreas Pfeiffer, Kathrin Thiele, Gerald Wimmer, Johannes Schenk
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引用次数: 1
摘要
由于欧盟雄心勃勃的气候目标,可以预见电弧炉(EAF)在未来的炼钢中将变得更加重要。由于炉渣发泡是高效工艺的决定性因素,因此在应用氢基直接还原铁(DRI)时,了解这一现象至关重要。因此,我们开发了一种方法来检查不同炉渣成分的发泡行为。熔化炉渣样品并加入碳载体。经过选定的反应时间后,将坩埚在液氮中淬火,在起泡的同时使其表面冻结。然后,将坩埚减半,进行金相检查和高度测量。测试了三种炉渣:氧化镁饱和的 EAF 炉渣、氧化镁不饱和的 EAF 炉渣和类似冶炼厂的电渣。使用数码电子显微镜和扫描电子显微镜以及能量色散 X 射线光谱仪对炉渣进行了比较,并对该方法进行了评估。冶炼炉炉渣没有泡沫,不受氧化铁含量的影响。相反,EAF 炉渣则具有良好的发泡性。
Laboratory Scale Evaluation of the Slag Foaming Behavior
Due to the ambitious climate targets of the European Union, one can expect that the electric arc furnace (EAF) will gain greater importance in the future of steelmaking. Since slag foaming is a decisive factor in an efficient process, understanding this phenomenon is essential when applying hydrogen-based direct reduced iron (DRI). Therefore, a method was developed to check different slag compositions concerning their foaming behavior. Slag samples are melted, and a carbon carrier is added. After a selected reaction time, the crucible is quenched in liquid nitrogen, superficially freezing the state while foaming. Afterward, it is halved, providing metallographic examination and height measurement possibilities. Three slags were tested, MgO-saturated EAF slag, MgO-unsaturated EAF slag, and electrical Smelter-like slag. Digital and scanning electron microscopy with energy dispersive x-ray spectroscopy are used to compare the slags and evaluate the method. The Smelter slag shows no foamability, unaffected by the FeO content. Contrary, good foamability can be observed for EAF slags.