城市地区黄檀产生 BVOC 二次污染物的可能性估算

Suteekan Maneejantra, Thanyaporn Charoenpun, S. Bualert, Parkpoom Choomanee, Suthee Janyasuthiwong, Waraporn Chommon
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摘要

气候变化会影响植物的生物挥发性有机化合物(BVOCs)排放,尤其是异戊二烯、α-蒎烯和β-蒎烯。这些化合物通过光化学反应在二次有机气溶胶潜能值(SOAP)和臭氧形成潜能值(OFP)中发挥着重要作用。泰国白天的气温通常高达 40°C,可能会对植物造成压力。所考虑的植物 Peltophorum pterocarpum 会释放大量 BVOCs,并在曼谷市区广泛种植。因此,本研究旨在研究白天与紫檀相关的 BVOC 浓度、SOAP 和 OFP 的变化。在当地时间 9:00 至 11:00 期间,使用动态封闭系统对 BVOCs(异戊二烯、α - 蒎烯和β - 蒎烯)进行采样,并使用带有火焰离子化检测器的气相色谱法进行分析。SOAP 和 OFP 是利用气溶胶分数系数和最大增量反应性估算得出的。结果显示,BVOC 的平均浓度为 4.68 μg/m3 ,这取决于温度和光照强度。最高 SOAP 和 OFP 分别为 1,367.10 和 188.58 μg/m3,这在很大程度上受 β - piene 的影响。这项研究有助于了解城市地区树木排放的 BVOCs 在二次污染物形成过程中的作用,从而选择 BVOC 排放量低的树种,并改进城市林区规划指南。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Potential Estimation of Secondary Pollutant Formation of BVOC from Peltophorum pterocarpum in Urban Area
Cimate change affects the emission of biogenic volatile organic compounds (BVOCs) from plants, especially isoprene, α-pinene, and β-pinene. These compounds play vital role in the secondary organic aerosol potential (SOAP) and ozone formation potential (OFP) through photochemical reactions. In Thailand, daytime temperatures typically reach up to 40°C resulting in potential plant stress. The considered plant Peltophorum pterocarpum, emits high levels of BVOCs and is widely cultivated in the urban areas of Bangkok. Consequently, this research aimed to study the variations in BVOC concentration, SOAP, and OFP associated with Peltophorum pterocarpum, during the daytime. The BVOCs (isoprene, α – pinene, and β – pinene) were sampled using a dynamic enclosure system from 9:00 to 11:00 local time and analyzed using gas chromatography with a flame ionization detector. SOAP and OFP were estimated using fractional aerosol coefficient and maximum incremental reactivity. The results revealed an average BVOC concentration of 4.68 μg/m3, which depended on temperature and light intensity. The highest SOAP and OFP were 1,367.10 and 188.58 μg/m3, respectively, which were largely influenced by β – piene. This study aids in understanding the role of secondary pollutant formation involving BVOCs emitted from trees in urban areas, which can lead to the selection of low BVOC-emitting tree species and improvement of guidelines for planning urban forest areas.
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