聚氨酯聚合物基体/微粒材料纳米复合材料

Fernanda Dias Neves
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摘要

目前,环境被认为是工业部门和社会关注的主要问题之一。就石油工业而言,可能发生的最大环境灾难之一就是大规模的石油泄漏,为了减少或尽量减少对环境造成的破坏,人们采用了各种清洁方法。因此,纳米复合材料旨在改变聚合物基体的机械、物理和化学特性。聚氨酯改性的主要重点是材料科学,其目标是获得微粒材料,使表面得以分化,降低表面能,增加聚合物夹层的层间间距。这种经过生产和改性的微粒材料与聚合物相混合,可以吸附原油,因为它具有疏水性,因此也具有亲有机性。决定有机化合物吸附程度的因素有:疏水性、孔隙率、分子结构和体积,以及吸附材料表面积的体积。因此,吸附剂必须能被疏水性化合物润湿,而不能被水润湿或稍有润湿。吸油材料必须具有表面积大、孔隙率高、亲油性好、留油能力强和易于使用等特点。聚氨酯具有上述几种特性,因此成为石油行业中一种令人感兴趣的吸油剂。目前的工作是研究如何获得这种纳米复合材料,利用微粒材料来防止碳氢化合物的泄漏或溢出。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nanocomposites with polyurethane polymer matrix/ particulate material
The environment is currently considered one of the main concerns of the industrial sector and society. In the particular case of the oil industry, one of the biggest environmental catastrophes that can happen are large oil spills, where to reduce or minimize the environmental damage caused, various cleaning methods are used. Thus, nanocomposites aim to change the mechanical, physical and chemical properties of polymer matrices. The main focus of modifying Polyurethanes has been directed to materials science, the objective of which is to obtain particulate materials, allowing surfaces to be differentiated, reducing surface energy and increasing interlayer spacing for polymer intercalation. This particulate material, produced and modified, interspersed with the Polymer, allows us to absorb crude oil, as it is hydrophobic and, consequently, organophilic. The factors that define the degree of sorption of organic compounds are: hydrophobicity, porosity, molecular structure and volume, and the volume of the surface area of the sorbent material. Therefore, the sorbent must be wettable by the hydrophobic compound and non-wettable or slightly wettable by water. Sorbent materials must have characteristics such as a large surface area, high porosity, good oleophilic character, as well as good oil retention capacity and ease of application. Polyurethane presents several of these characteristics, making it an interesting sorbent for the oil sector. The present work studies the obtaining of these nanocomposites, using a particulate material to combat leaks or spills of hydrocarbons.
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