氨基酸衍生物的分子内和分子间Friedel-Crafts立体残基酰化反应

IF 1.7 3区化学 Q3 CHEMISTRY, ORGANIC

Current Organic Chemistry Pub Date : 2024-05-14 DOI:10.2174/0113852728317263240510114622

Zetryana Puteri Tachrim, Makoto Hashimoto

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引用次数: 0

摘要

这里愿意介绍天然或非天然氨基酸的弗里德尔-卡夫酰化反应。根据氨基酸的主要骨架，可以区分典型的分子内和分子间 Friedel-Crafts 反应。独特的氨基酸总体结构有助于其羧基和侧链之间的反应。根据弗里德尔-卡夫斯反应条件的不同，氨基酸的光学保留时间也会不同。这一观点有助于这一百年反应在有机化学领域的发展。

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The Intra- and Intermolecular Friedel-Crafts Acylation of Amino Acid Derivatives in Stereo-Retarded Manner

The Friedel-Crafts acylation of natural or unnatural amino acids in stereo-retarded manner is willing to prescribed here. Depending on its main skeleton, the typical intra- and intermolecular Friedel-Crafts reaction of amino acids can be differentiated. The unique amino acid’s general structure can contribute to the reaction between its carboxyl group and the side chain. Depending on the Friedel-Crafts reaction condition, the amino acid’s optical retention can be retarded. This perspective can contribute to the development of this one-century reaction in the field of organic chemistry.

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来源期刊

Current Organic Chemistry 化学-有机化学

CiteScore

3.70

自引率

7.70%

发文量

审稿时长

1 months

期刊介绍： Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.