{"title":"作为双功能材料的掺铂碳纳米管催化剂:其在制氢和超级电容器中的应用","authors":"Tulin Avci Hansu","doi":"10.21926/cr.2402005","DOIUrl":null,"url":null,"abstract":"In this study, by producing bifunctional material, hydrolysis, and supercapacitor applications were investigated. The carbon nanotube-supported Pt catalyst was prepared using the sodium borohydride (NaBH4) reduction. Surface characterization of the synthesized Pt/CNT catalyst was performed using scanning electron microscopy-energy dıstrıbutıon X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Hydrolysis experiments were performed after deciding on the appropriate atomic ratio from the Pt/CNT catalysts synthesized in different nuclear ratios. The parameters affecting the hydrogen production from NaBH4 were examined. As a result of the kinetic calculations, the initial rates of reaction for 30°C and 60°C were calculated as 21949,69 mlH2gcatmin-1 and 70018,18 mlH2gcatmin-1. Galvastonic charge-discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were used as characterization techniques for the use of Pt/CNT catalysts as electrodes in supercapacitor applications. The specific capacitance value of 7% Pt/CNT catalyst at 1 A/g current density was calculated as 57,78 F/g. Energy and power density were calculated as 8,025 Wh/kg and 963 W/kg, respectively. Therefore, this catalyst is called a “cap-cat” with capacitor properties. The catalyst used in this study is promising for this recently studied topic.","PeriodicalId":178524,"journal":{"name":"Catalysis Research","volume":"28 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Remarkable Pt Doped CNT Catalyst as a Double Functional Material: Its Application for Hydrogen Production and Supercapacitor\",\"authors\":\"Tulin Avci Hansu\",\"doi\":\"10.21926/cr.2402005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, by producing bifunctional material, hydrolysis, and supercapacitor applications were investigated. The carbon nanotube-supported Pt catalyst was prepared using the sodium borohydride (NaBH4) reduction. Surface characterization of the synthesized Pt/CNT catalyst was performed using scanning electron microscopy-energy dıstrıbutıon X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Hydrolysis experiments were performed after deciding on the appropriate atomic ratio from the Pt/CNT catalysts synthesized in different nuclear ratios. The parameters affecting the hydrogen production from NaBH4 were examined. As a result of the kinetic calculations, the initial rates of reaction for 30°C and 60°C were calculated as 21949,69 mlH2gcatmin-1 and 70018,18 mlH2gcatmin-1. Galvastonic charge-discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were used as characterization techniques for the use of Pt/CNT catalysts as electrodes in supercapacitor applications. The specific capacitance value of 7% Pt/CNT catalyst at 1 A/g current density was calculated as 57,78 F/g. Energy and power density were calculated as 8,025 Wh/kg and 963 W/kg, respectively. Therefore, this catalyst is called a “cap-cat” with capacitor properties. The catalyst used in this study is promising for this recently studied topic.\",\"PeriodicalId\":178524,\"journal\":{\"name\":\"Catalysis Research\",\"volume\":\"28 3\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21926/cr.2402005\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21926/cr.2402005","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Remarkable Pt Doped CNT Catalyst as a Double Functional Material: Its Application for Hydrogen Production and Supercapacitor
In this study, by producing bifunctional material, hydrolysis, and supercapacitor applications were investigated. The carbon nanotube-supported Pt catalyst was prepared using the sodium borohydride (NaBH4) reduction. Surface characterization of the synthesized Pt/CNT catalyst was performed using scanning electron microscopy-energy dıstrıbutıon X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Hydrolysis experiments were performed after deciding on the appropriate atomic ratio from the Pt/CNT catalysts synthesized in different nuclear ratios. The parameters affecting the hydrogen production from NaBH4 were examined. As a result of the kinetic calculations, the initial rates of reaction for 30°C and 60°C were calculated as 21949,69 mlH2gcatmin-1 and 70018,18 mlH2gcatmin-1. Galvastonic charge-discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were used as characterization techniques for the use of Pt/CNT catalysts as electrodes in supercapacitor applications. The specific capacitance value of 7% Pt/CNT catalyst at 1 A/g current density was calculated as 57,78 F/g. Energy and power density were calculated as 8,025 Wh/kg and 963 W/kg, respectively. Therefore, this catalyst is called a “cap-cat” with capacitor properties. The catalyst used in this study is promising for this recently studied topic.