将二氧化碳催化氢化作为生产有价值化学品的一种方法

IF 0.7 Q4 ENGINEERING, CHEMICAL

Catalysis in Industry Pub Date : 2024-05-13 DOI:10.1134/S2070050424010045

I. A. Makaryan, I. V. Sedov, V. I. Savchenko

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引用次数: 0

摘要

摘要本综述旨在总结和比较分析最近有关研究二氧化碳通过催化加氢转化为甲醇、二甲醚和 C2+ 碳氢化合物（特别是烯烃）的报道。研究表明，使这些过程具有高活性和高选择性的主要方法是有针对性地设计催化剂和选择加氢过程的条件，特别是使用超临界二氧化碳和二氧化碳活化的传统物理化学方法（电催化、光催化）的替代程序。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Catalytic Hydrogenation of Carbon Dioxide as a Method to Produce Valuable Chemicals

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Catalytic Hydrogenation of Carbon Dioxide as a Method to Produce Valuable Chemicals

The aim of this review is to summarize and comparatively analyze recent reports on studying carbon dioxide conversion to methanol, dimethyl ether, and C₂₊ hydrocarbons, in particular, olefins, by catalytic hydrogenation. It is shown that the main approaches to providing high activity and selectivity of these processes are the targeted design of catalysts and the selection of conditions for hydrogenation processes, in particular, the use of supercritical CO₂ and procedures that are alternative to conventional physicochemical methods for CO₂ activation (electrocatalysis, photocatalysis).

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来源期刊

Catalysis in Industry ENGINEERING, CHEMICAL-

CiteScore

1.30

自引率

14.30%

发文量

期刊介绍： The journal covers the following topical areas: Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.