基于竞争性实验结果的催化剂转化动态可视化

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Kinetics and Catalysis Pub Date : 2024-05-09 DOI:10.1134/S002315842360116X

A. A. Kurokhtina, E. V. Larina, N. A. Lagoda, A. F. Schmidt

{"title":"基于竞争性实验结果的催化剂转化动态可视化","authors":"A. A. Kurokhtina, E. V. Larina, N. A. Lagoda, A. F. Schmidt","doi":"10.1134/S002315842360116X","DOIUrl":null,"url":null,"abstract":"<p>This paper demonstrates that relative reactivity estimated under competition of several similar substrates can be applied to visualize the dynamics of changes in a catalyst under the conditions of a complex catalytic process. The fundamental advantage of the proposed approach is that the state of an active catalyst can be monitored throughout the catalytic reaction without differentiation of the kinetic data on the concentrations of reacted substances.</p>","PeriodicalId":682,"journal":{"name":"Kinetics and Catalysis","volume":"65 2","pages":"168 - 177"},"PeriodicalIF":1.3000,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Visualization of the Dynamics of Catalyst Transformations Based on the Results of Competing Experiments\",\"authors\":\"A. A. Kurokhtina, E. V. Larina, N. A. Lagoda, A. F. Schmidt\",\"doi\":\"10.1134/S002315842360116X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This paper demonstrates that relative reactivity estimated under competition of several similar substrates can be applied to visualize the dynamics of changes in a catalyst under the conditions of a complex catalytic process. The fundamental advantage of the proposed approach is that the state of an active catalyst can be monitored throughout the catalytic reaction without differentiation of the kinetic data on the concentrations of reacted substances.</p>\",\"PeriodicalId\":682,\"journal\":{\"name\":\"Kinetics and Catalysis\",\"volume\":\"65 2\",\"pages\":\"168 - 177\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-05-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Kinetics and Catalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S002315842360116X\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kinetics and Catalysis","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S002315842360116X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

摘要本文论证了在几种类似底物竞争下估算的相对反应活性可用于观察催化剂在复杂催化过程条件下的动态变化。所提方法的基本优点是可以在整个催化反应过程中监测活性催化剂的状态，而无需区分反应物质浓度的动力学数据。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Visualization of the Dynamics of Catalyst Transformations Based on the Results of Competing Experiments

查看原文本刊更多论文

Visualization of the Dynamics of Catalyst Transformations Based on the Results of Competing Experiments

This paper demonstrates that relative reactivity estimated under competition of several similar substrates can be applied to visualize the dynamics of changes in a catalyst under the conditions of a complex catalytic process. The fundamental advantage of the proposed approach is that the state of an active catalyst can be monitored throughout the catalytic reaction without differentiation of the kinetic data on the concentrations of reacted substances.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Kinetics and Catalysis 化学-物理化学

CiteScore

2.10

自引率

27.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.