麻增强聚丙烯复合材料:碱性和偶联剂处理的影响

Siripan Metanawin, Maneerat Charoenchan, Tanapak Metanawin
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引用次数: 0

摘要

麻纤维增强聚丙烯复合材料是在聚丙烯-接枝-马来酸酐(PP-g-MA)和硅烷作为偶联剂的情况下,通过双螺杆挤出机挤出,然后通过压缩成型制成的。麻纤维是在双螺杆挤出机之前通过氢氧化钠处理获得的。使用万能试验机、扫描电子显微镜、差示扫描量热仪、X 射线衍射仪和傅立叶变换红外光谱仪对 PP/ 大麻复合材料进行了分析。在大多数大麻含量下,PP/MA/大麻的机械性能都优于 PP/Si/ 大麻。PP/MA/Hemp 的扫描电子显微镜图像显示,PP/MA/Hemp30 的界面粘结性能优异,没有纤维拉断现象。然而,PP/Si/Hemp 的纤维断裂和部分纤维拉断,纤维周围出现空隙,表明 PP 基体的粘结性较差。PP/Hemp 复合材料的官能团显示出麻纤维与聚丙烯反应的 -OH 纤维素结果峰。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The hemp-reinforced polypropylene composite: Effect of the alkaline and coupling agents treatment
The hemp-reinforced polypropylene composite was produced by the twin-screw extrusion in the presence of polypropylene-graft-maleic anhydride (PP-g-MA) and silane as coupling agents and subsequence by the compression molding. The hemp fiber was obtained by sodium hydroxide treatment prior to the twin-screw extruder. The PP/Hemp composite was analyzed using a universal testing machine, scanning electron microscope, differential scanning calorimetry, X-ray diffraction, and Fourier transform infrared spectroscopy. The mechanical properties of the PP/MA/Hemp demonstrated a better result than that of PP/Si/Hemp in most hemp contents. The SEM images of the PP/MA/Hemp exhibited excellent interfacial bonding in PP/MA/Hemp30 without fiber pullouts. However, the fiber breakage and some fiber pullout with gaps around the fiber of PP/Si/Hemp indicate the poor bonding of the PP matrix. The functional group of the PP/Hemp composite showed the –OH cellulose result peak of the reaction between hemp fibers and polypropylene.
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