Guy Crundwell , Rachel A. Christiana , Paul Ouellette , Andrew F. Giorgetti , M. Zeller (Editor)
{"title":"双[2,3-双-(硫酚-2-基)吡啶并[3,4-b]吡嗪]-高氯酸银(I)甲醇二溶液。","authors":"Guy Crundwell , Rachel A. Christiana , Paul Ouellette , Andrew F. Giorgetti , M. Zeller (Editor)","doi":"10.1107/S2414314624003444","DOIUrl":null,"url":null,"abstract":"<div><p>The structure of bis[2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine]silver(I) perchlorate methanol disolvate is monoclinic. The Ag atom coordinates pyrido N atoms and is two-coordinate; however, the Ag atom has nearby O atoms that can be assumed to be weakly bonding – one from the perchlorate anion and one from the methanol solvate. One of the thienyl groups of a 2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%.</p></div><div><p>The title compound, [Ag(C<sub>15</sub>H<sub>9</sub>N<sub>3</sub>S<sub>2</sub>)<sub>2</sub>]ClO<sub>4</sub>·2CH<sub>3</sub>OH, is monoclinic. The Ag<sup>I</sup> atom is coordinated by pyrido N atoms and is two-coordinate; however, the Ag<sup>I</sup> atom has nearby O atoms that can be assumed to be weakly bonded – one from the perchlorate anion and one from the methanol solvate molecule. One of the thienyl groups on a 2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (217KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11074545/pdf/","citationCount":"0","resultStr":"{\"title\":\"Bis[2,3-bis(thiophen-2-yl)pyrido[3,4-b]pyrazine]silver(I) perchlorate methanol disolvate\",\"authors\":\"Guy Crundwell , Rachel A. Christiana , Paul Ouellette , Andrew F. Giorgetti , M. Zeller (Editor)\",\"doi\":\"10.1107/S2414314624003444\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The structure of bis[2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine]silver(I) perchlorate methanol disolvate is monoclinic. The Ag atom coordinates pyrido N atoms and is two-coordinate; however, the Ag atom has nearby O atoms that can be assumed to be weakly bonding – one from the perchlorate anion and one from the methanol solvate. One of the thienyl groups of a 2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%.</p></div><div><p>The title compound, [Ag(C<sub>15</sub>H<sub>9</sub>N<sub>3</sub>S<sub>2</sub>)<sub>2</sub>]ClO<sub>4</sub>·2CH<sub>3</sub>OH, is monoclinic. The Ag<sup>I</sup> atom is coordinated by pyrido N atoms and is two-coordinate; however, the Ag<sup>I</sup> atom has nearby O atoms that can be assumed to be weakly bonded – one from the perchlorate anion and one from the methanol solvate molecule. One of the thienyl groups on a 2,3-bis(thiophen-2-yl)pyrido[3,4-<em>b</em>]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (217KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11074545/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000208\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000208","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
标题化合物[Ag(C15H9N3S2)2]ClO4-2CH3OH 呈单斜型。AgI 原子由吡啶 N 原子配位，是二配位原子；不过，AgI 原子附近的 O 原子可以认为是弱键，一个来自高氯酸盐阴离子，一个来自甲醇溶剂分子。在 2,3-双（硫代-苯-2-基）吡啶并[3,4-b]吡嗪上的一个噻吩基团是无序翻转的，精制后的占位率分别为 68.4 (6) % 和 31.6 (6)%。
The structure of bis[2,3-bis(thiophen-2-yl)pyrido[3,4-b]pyrazine]silver(I) perchlorate methanol disolvate is monoclinic. The Ag atom coordinates pyrido N atoms and is two-coordinate; however, the Ag atom has nearby O atoms that can be assumed to be weakly bonding – one from the perchlorate anion and one from the methanol solvate. One of the thienyl groups of a 2,3-bis(thiophen-2-yl)pyrido[3,4-b]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%.
The title compound, [Ag(C15H9N3S2)2]ClO4·2CH3OH, is monoclinic. The AgI atom is coordinated by pyrido N atoms and is two-coordinate; however, the AgI atom has nearby O atoms that can be assumed to be weakly bonded – one from the perchlorate anion and one from the methanol solvate molecule. One of the thienyl groups on a 2,3-bis(thiophen-2-yl)pyrido[3,4-b]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%.
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