O. S. Vezo, A. V. Voitylov, V. V. Vojtylov, M. P. Petrov, A. A. Trusov
{"title":"含金刚石/无定形碳复合颗粒的水溶液的折射率","authors":"O. S. Vezo, A. V. Voitylov, V. V. Vojtylov, M. P. Petrov, A. A. Trusov","doi":"10.1134/S1061933X24600040","DOIUrl":null,"url":null,"abstract":"<p>Refractometric studies of hydrosols containing diamond nanoparticles have been carried out in this work. The samples for the study have been obtained from a statically synthesized diamond powder preliminarily subjected to standard purification by washing with strong acids and sonication. After additional repeated washing, centrifugation, sonication, and settling for a month, samples, whose particles contained different fractions of amorphous carbon, have been obtained. The particle size in the obtained samples was smaller than 100 nm. To analyze the data of refractometric measurements, equations have been derived that make it possible to determine the fraction of amorphous carbon in the particles and to calculate the thickness of its layer on the particle surface from the results of studying the refractive index and density of the sols of diamond particles. The data of the refractometric studies have been used to determine the ratios between the fractions of crystalline diamond and amorphous carbon in the particles. The performed studies have shown that the refractometric analysis of particle composition can be used to control the quality of industrially produced nanodiamonds.</p>","PeriodicalId":521,"journal":{"name":"Colloid Journal","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Refraction of Hydrosols Containing Diamond/Amorphous Carbon Composite Particles\",\"authors\":\"O. S. Vezo, A. V. Voitylov, V. V. Vojtylov, M. P. Petrov, A. A. Trusov\",\"doi\":\"10.1134/S1061933X24600040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Refractometric studies of hydrosols containing diamond nanoparticles have been carried out in this work. The samples for the study have been obtained from a statically synthesized diamond powder preliminarily subjected to standard purification by washing with strong acids and sonication. After additional repeated washing, centrifugation, sonication, and settling for a month, samples, whose particles contained different fractions of amorphous carbon, have been obtained. The particle size in the obtained samples was smaller than 100 nm. To analyze the data of refractometric measurements, equations have been derived that make it possible to determine the fraction of amorphous carbon in the particles and to calculate the thickness of its layer on the particle surface from the results of studying the refractive index and density of the sols of diamond particles. The data of the refractometric studies have been used to determine the ratios between the fractions of crystalline diamond and amorphous carbon in the particles. The performed studies have shown that the refractometric analysis of particle composition can be used to control the quality of industrially produced nanodiamonds.</p>\",\"PeriodicalId\":521,\"journal\":{\"name\":\"Colloid Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloid Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1061933X24600040\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid Journal","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061933X24600040","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Refraction of Hydrosols Containing Diamond/Amorphous Carbon Composite Particles
Refractometric studies of hydrosols containing diamond nanoparticles have been carried out in this work. The samples for the study have been obtained from a statically synthesized diamond powder preliminarily subjected to standard purification by washing with strong acids and sonication. After additional repeated washing, centrifugation, sonication, and settling for a month, samples, whose particles contained different fractions of amorphous carbon, have been obtained. The particle size in the obtained samples was smaller than 100 nm. To analyze the data of refractometric measurements, equations have been derived that make it possible to determine the fraction of amorphous carbon in the particles and to calculate the thickness of its layer on the particle surface from the results of studying the refractive index and density of the sols of diamond particles. The data of the refractometric studies have been used to determine the ratios between the fractions of crystalline diamond and amorphous carbon in the particles. The performed studies have shown that the refractometric analysis of particle composition can be used to control the quality of industrially produced nanodiamonds.
期刊介绍：
Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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