W. Hao, V. S. Molchanov, Yu. M. Chesnokov, P. R. Podlesnyi, O. E. Philippova
{"title":"基于甜菜碱的表面活性剂和具有相同疏水基团的带电荷叔胺的蠕虫状胶束中的静电相互作用效应","authors":"W. Hao, V. S. Molchanov, Yu. M. Chesnokov, P. R. Podlesnyi, O. E. Philippova","doi":"10.1134/S1061933X23601373","DOIUrl":null,"url":null,"abstract":"<p>The viscoelastic properties and structure of solutions of mixed wormlike micelles based on a zwitterionic surfactant, oleylamidopropyldimethylcarboxybetaine (OAPB), and positively charged oleylamidopropyldimethylamine (OAPA) have been studied at different ratios between the components. At a small fraction of the cationic surfactant, OAPA, the solution exhibits viscoelastic properties characteristic of semidiluted solutions of entangled wormlike micelles, the presence of which has been confirmed by cryogenic electron microscopy data. It has been found that, as the molar fraction of the charged surfactant increases to 0.1, the viscosity and relaxation time of the solutions decrease by a factor of three, and the values of the storage modulus remain unchanged at short stress action times. The studied surfactants have a similar structure; therefore, when replacing zwitterionic OAPB molecules by positively charged OAPA molecules, the main factor of variations in the properties and structure is the enhancement of the electrostatic repulsion on the micelle surface. It has been shown that this factor leads to a decrease in the average length of micelles and an increase in their number, which have a weak effect on the rheological properties of the system as long as the length of the micelles is larger than the length of the subchains in the network. With an increase in the molar fraction of OAPA from 0.1 to 0.5, the viscosity and relaxation time drop drastically by several orders of magnitude and the viscoelastic response of the solution is lost; i.e., the network is destroyed. This transition from a semidilute solution to a dilute one is explained by a decrease in the length of the wormlike micelles and the formation of spherical ones. Cryogenic electron microscopy images have confirmed the formation of a mixture of long and short wormlike micelles with spherical micelles at an OAPA molar fraction of 0.5.</p>","PeriodicalId":521,"journal":{"name":"Colloid Journal","volume":"86 2","pages":"306 - 314"},"PeriodicalIF":1.4000,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1061933X23601373.pdf","citationCount":"0","resultStr":"{\"title\":\"Effect of Electrostatic Interactions in Wormlike Micelles of Surfactants Based on Betaine and Charged Tertiary Amine with the Same Hydrophobic Groups\",\"authors\":\"W. Hao, V. S. Molchanov, Yu. M. Chesnokov, P. R. Podlesnyi, O. E. Philippova\",\"doi\":\"10.1134/S1061933X23601373\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The viscoelastic properties and structure of solutions of mixed wormlike micelles based on a zwitterionic surfactant, oleylamidopropyldimethylcarboxybetaine (OAPB), and positively charged oleylamidopropyldimethylamine (OAPA) have been studied at different ratios between the components. At a small fraction of the cationic surfactant, OAPA, the solution exhibits viscoelastic properties characteristic of semidiluted solutions of entangled wormlike micelles, the presence of which has been confirmed by cryogenic electron microscopy data. It has been found that, as the molar fraction of the charged surfactant increases to 0.1, the viscosity and relaxation time of the solutions decrease by a factor of three, and the values of the storage modulus remain unchanged at short stress action times. The studied surfactants have a similar structure; therefore, when replacing zwitterionic OAPB molecules by positively charged OAPA molecules, the main factor of variations in the properties and structure is the enhancement of the electrostatic repulsion on the micelle surface. It has been shown that this factor leads to a decrease in the average length of micelles and an increase in their number, which have a weak effect on the rheological properties of the system as long as the length of the micelles is larger than the length of the subchains in the network. With an increase in the molar fraction of OAPA from 0.1 to 0.5, the viscosity and relaxation time drop drastically by several orders of magnitude and the viscoelastic response of the solution is lost; i.e., the network is destroyed. This transition from a semidilute solution to a dilute one is explained by a decrease in the length of the wormlike micelles and the formation of spherical ones. Cryogenic electron microscopy images have confirmed the formation of a mixture of long and short wormlike micelles with spherical micelles at an OAPA molar fraction of 0.5.</p>\",\"PeriodicalId\":521,\"journal\":{\"name\":\"Colloid Journal\",\"volume\":\"86 2\",\"pages\":\"306 - 314\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1134/S1061933X23601373.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloid Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1061933X23601373\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid Journal","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061933X23601373","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Effect of Electrostatic Interactions in Wormlike Micelles of Surfactants Based on Betaine and Charged Tertiary Amine with the Same Hydrophobic Groups
The viscoelastic properties and structure of solutions of mixed wormlike micelles based on a zwitterionic surfactant, oleylamidopropyldimethylcarboxybetaine (OAPB), and positively charged oleylamidopropyldimethylamine (OAPA) have been studied at different ratios between the components. At a small fraction of the cationic surfactant, OAPA, the solution exhibits viscoelastic properties characteristic of semidiluted solutions of entangled wormlike micelles, the presence of which has been confirmed by cryogenic electron microscopy data. It has been found that, as the molar fraction of the charged surfactant increases to 0.1, the viscosity and relaxation time of the solutions decrease by a factor of three, and the values of the storage modulus remain unchanged at short stress action times. The studied surfactants have a similar structure; therefore, when replacing zwitterionic OAPB molecules by positively charged OAPA molecules, the main factor of variations in the properties and structure is the enhancement of the electrostatic repulsion on the micelle surface. It has been shown that this factor leads to a decrease in the average length of micelles and an increase in their number, which have a weak effect on the rheological properties of the system as long as the length of the micelles is larger than the length of the subchains in the network. With an increase in the molar fraction of OAPA from 0.1 to 0.5, the viscosity and relaxation time drop drastically by several orders of magnitude and the viscoelastic response of the solution is lost; i.e., the network is destroyed. This transition from a semidilute solution to a dilute one is explained by a decrease in the length of the wormlike micelles and the formation of spherical ones. Cryogenic electron microscopy images have confirmed the formation of a mixture of long and short wormlike micelles with spherical micelles at an OAPA molar fraction of 0.5.
期刊介绍：
Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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