有机合成中以球磨法进行压电介导的机械氧化反应综述

IF 1.7 3区 化学 Q3 CHEMISTRY, ORGANIC
Shan Jiang, Miao Wang
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引用次数: 0

摘要

:最近,有机合成中提出并发展了机械氧化还原化学的概念。机械氧化还原化学在概念上类似于光催化剂反应系统,其中压电材料以类似于光氧化催化的方式引入反应系统。这些反应的特点是能够生成高价值的自由基,而不需要无水和厌氧等苛刻的反应条件、昂贵的光催化剂以及溶剂的使用,这使得这些转化具有高度的工业适用性。此外,机械氧化还原化学也是一个新兴的跨学科研究领域,它将材料化学与合成化学相结合,创造出更多有用的反应。本综述全面总结了迄今为止在有机合成中通过球磨进行压电介导的机械氧化还原反应的具体转化和相关机理方面取得的进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Review on Piezoelectric-Mediated Mechanoredox Reactions by Ball Milling in Organic Synthesis
: Recently, the concept of mechanoredox chemistry has been proposed and well-developed in organic synthesis. Mechanoredox chemistry is conceptually similar to a photocatalyst reaction system, where piezoelectric materials are introduced to the reaction system in a manner analogous to photoredox catalysis. These reactions feature the ability to generate high-value radicals that do not require harsh reaction conditions of anhydrous and anaerobic conditions, an expensive photocatalyst, and the use of solvents, which renders these transformations highly industrially applicable. In addition, mechanoredox chemistry is also an emerging interdisciplinary research field that combines material chemistry with synthetic chemistry to create more useful reactions. This review provides a comprehensive summary of progress to date in the specific transformation and related mechanisms of piezoelectric-mediated mechanoredox reactions by ball milling in organic synthesis.
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来源期刊
Current Organic Chemistry
Current Organic Chemistry 化学-有机化学
CiteScore
3.70
自引率
7.70%
发文量
76
审稿时长
1 months
期刊介绍: Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.
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