利用掺入咔唑的 Regioisomeric 合成策略为 Perovskite 太阳能电池设计空穴传输材料

IF 3 4区 化学 Q3 CHEMISTRY, PHYSICAL
Dr. Tamer Yeşil, Assist. Prof. Adem Mutlu, M. Sc. Sevdiye Başak Turgut, Assoc. Prof. Burak Gültekin, Prof. Dr. Ceylan Zafer
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引用次数: 0

摘要

合成了两种新的 p 型分子,即 TAT-TY3 和 TAT-TY4,它们具有三氮杂环戊烯端帽和咔唑 π 桥。根据 2,7- 和 3,6-咔唑共轭途径,对合成材料的光物理和电化学特性进行了比较研究。光学表征显示,三氮杂戊烯通过咔唑分子的非键电子脱位产生了影响,导致 n-π* 能量跃迁对应的吸收强度显著增加,三氮杂戊烯分子发生红移。因此,测得 TAT-TY3 和 TAT-TY4 的光带隙分别为 3.0 和 3.2 eV。此外,由于 2,7- 和 3,6-咔唑分子的电化学行为不同,这两种分子的第一氧化电位也有很大差异。经测量,TAT-TY3 的最高占位分子轨道(HOMO)电平为 -5.02 eV,而 TAT-TY4 的最高占位分子轨道电平为 -4.67 eV。利用稳态和时间分辨光致发光光谱探索了空穴萃取特性,结果表明,由于 HOMO 能级的更好排列,TAT-TY3/Perovskite 界面之间的电荷转移得到了增强。在三阳离子过氧化物太阳能电池中成功鉴定了空穴传输材料(HTMs)的光伏性能,Spiro-OMeTAD、TAT-TY3 和 TAT-TY4 的效率分别高达 17.9%、16.2% 和 9.8%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Utilizing a Carbazole-Incorporated Regioisomeric Synthesis Strategy to Design Hole Transporting Materials for Perovskite Solar Cells

Utilizing a Carbazole-Incorporated Regioisomeric Synthesis Strategy to Design Hole Transporting Materials for Perovskite Solar Cells

Two new p-type molecules, namely TAT-TY3 and TAT-TY4, featuring triazatruxene endcaps and carbazole π-bridges, were synthesized. The photophysical and electrochemical properties of synthesized materials were comparatively investigated based on their 2,7- and 3,6-carbazole conjugation pathways. Optical characterizations revealed the impact of non-bonding electron delocalization of triazatruxene through carbazole moieties, resulting in a significant increase in absorption intensity corresponding to n-π* energy transitions and a red shift of triazatruxene moieties. Consequently, the optical band gaps of TAT-TY3 and TAT-TY4 were measured at 3.0 and 3.2 eV, respectively. Moreover, the molecules′ first oxidation potentials exhibited a drastic difference due to the electrochemical behavior of 2,7- and 3,6-carbazole moieties. The highest occupied molecular orbital (HOMO) level for TAT-TY3 was measured to be −5.02 eV, while for TAT-TY4, it was measured as −4.67 eV. Hole-extraction properties were explored using steady-state and time-resolved photoluminescence spectroscopy, revealing enhanced charge transfer between the TAT-TY3/Perovskite interface due to the better alignment of HOMO energy levels. The photovoltaic performances of the hole-transporting materials (HTMs) were successfully characterized in triple-cation perovskite solar cells and efficiencies of up to 17.9 %, 16.2 %, and 9.8 % were achieved for Spiro-OMeTAD, TAT-TY3, and TAT-TY4, respectively.

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来源期刊
ChemPhotoChem
ChemPhotoChem Chemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
期刊介绍: Light plays a crucial role in natural processes and leads to exciting phenomena in molecules and materials. ChemPhotoChem welcomes exceptional international research in the entire scope of pure and applied photochemistry, photobiology, and photophysics. Our thorough editorial practices aid us in publishing authoritative research fast. We support the photochemistry community to be a leading light in science. We understand the huge pressures the scientific community is facing every day and we want to support you. Chemistry Europe is an association of 16 chemical societies from 15 European countries. Run by chemists, for chemists—we evaluate, publish, disseminate, and amplify the scientific excellence of chemistry researchers from around the globe.
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