Dr. Tamer Yeşil, Assist. Prof. Adem Mutlu, M. Sc. Sevdiye Başak Turgut, Assoc. Prof. Burak Gültekin, Prof. Dr. Ceylan Zafer
{"title":"利用掺入咔唑的 Regioisomeric 合成策略为 Perovskite 太阳能电池设计空穴传输材料","authors":"Dr. Tamer Yeşil, Assist. Prof. Adem Mutlu, M. Sc. Sevdiye Başak Turgut, Assoc. Prof. Burak Gültekin, Prof. Dr. Ceylan Zafer","doi":"10.1002/cptc.202400040","DOIUrl":null,"url":null,"abstract":"<p>Two new p-type molecules, namely TAT-TY3 and TAT-TY4, featuring triazatruxene endcaps and carbazole π-bridges, were synthesized. The photophysical and electrochemical properties of synthesized materials were comparatively investigated based on their 2,7- and 3,6-carbazole conjugation pathways. Optical characterizations revealed the impact of non-bonding electron delocalization of triazatruxene through carbazole moieties, resulting in a significant increase in absorption intensity corresponding to n-π* energy transitions and a red shift of triazatruxene moieties. Consequently, the optical band gaps of TAT-TY3 and TAT-TY4 were measured at 3.0 and 3.2 eV, respectively. Moreover, the molecules′ first oxidation potentials exhibited a drastic difference due to the electrochemical behavior of 2,7- and 3,6-carbazole moieties. The highest occupied molecular orbital (HOMO) level for TAT-TY3 was measured to be −5.02 eV, while for TAT-TY4, it was measured as −4.67 eV. Hole-extraction properties were explored using steady-state and time-resolved photoluminescence spectroscopy, revealing enhanced charge transfer between the TAT-TY3/Perovskite interface due to the better alignment of HOMO energy levels. The photovoltaic performances of the hole-transporting materials (HTMs) were successfully characterized in triple-cation perovskite solar cells and efficiencies of up to 17.9 %, 16.2 %, and 9.8 % were achieved for Spiro-OMeTAD, TAT-TY3, and TAT-TY4, respectively.</p>","PeriodicalId":10108,"journal":{"name":"ChemPhotoChem","volume":"8 9","pages":""},"PeriodicalIF":3.0000,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Utilizing a Carbazole-Incorporated Regioisomeric Synthesis Strategy to Design Hole Transporting Materials for Perovskite Solar Cells\",\"authors\":\"Dr. Tamer Yeşil, Assist. Prof. Adem Mutlu, M. Sc. Sevdiye Başak Turgut, Assoc. Prof. Burak Gültekin, Prof. Dr. Ceylan Zafer\",\"doi\":\"10.1002/cptc.202400040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Two new p-type molecules, namely TAT-TY3 and TAT-TY4, featuring triazatruxene endcaps and carbazole π-bridges, were synthesized. The photophysical and electrochemical properties of synthesized materials were comparatively investigated based on their 2,7- and 3,6-carbazole conjugation pathways. Optical characterizations revealed the impact of non-bonding electron delocalization of triazatruxene through carbazole moieties, resulting in a significant increase in absorption intensity corresponding to n-π* energy transitions and a red shift of triazatruxene moieties. Consequently, the optical band gaps of TAT-TY3 and TAT-TY4 were measured at 3.0 and 3.2 eV, respectively. Moreover, the molecules′ first oxidation potentials exhibited a drastic difference due to the electrochemical behavior of 2,7- and 3,6-carbazole moieties. The highest occupied molecular orbital (HOMO) level for TAT-TY3 was measured to be −5.02 eV, while for TAT-TY4, it was measured as −4.67 eV. Hole-extraction properties were explored using steady-state and time-resolved photoluminescence spectroscopy, revealing enhanced charge transfer between the TAT-TY3/Perovskite interface due to the better alignment of HOMO energy levels. The photovoltaic performances of the hole-transporting materials (HTMs) were successfully characterized in triple-cation perovskite solar cells and efficiencies of up to 17.9 %, 16.2 %, and 9.8 % were achieved for Spiro-OMeTAD, TAT-TY3, and TAT-TY4, respectively.</p>\",\"PeriodicalId\":10108,\"journal\":{\"name\":\"ChemPhotoChem\",\"volume\":\"8 9\",\"pages\":\"\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-05-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemPhotoChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cptc.202400040\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemPhotoChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cptc.202400040","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Utilizing a Carbazole-Incorporated Regioisomeric Synthesis Strategy to Design Hole Transporting Materials for Perovskite Solar Cells
Two new p-type molecules, namely TAT-TY3 and TAT-TY4, featuring triazatruxene endcaps and carbazole π-bridges, were synthesized. The photophysical and electrochemical properties of synthesized materials were comparatively investigated based on their 2,7- and 3,6-carbazole conjugation pathways. Optical characterizations revealed the impact of non-bonding electron delocalization of triazatruxene through carbazole moieties, resulting in a significant increase in absorption intensity corresponding to n-π* energy transitions and a red shift of triazatruxene moieties. Consequently, the optical band gaps of TAT-TY3 and TAT-TY4 were measured at 3.0 and 3.2 eV, respectively. Moreover, the molecules′ first oxidation potentials exhibited a drastic difference due to the electrochemical behavior of 2,7- and 3,6-carbazole moieties. The highest occupied molecular orbital (HOMO) level for TAT-TY3 was measured to be −5.02 eV, while for TAT-TY4, it was measured as −4.67 eV. Hole-extraction properties were explored using steady-state and time-resolved photoluminescence spectroscopy, revealing enhanced charge transfer between the TAT-TY3/Perovskite interface due to the better alignment of HOMO energy levels. The photovoltaic performances of the hole-transporting materials (HTMs) were successfully characterized in triple-cation perovskite solar cells and efficiencies of up to 17.9 %, 16.2 %, and 9.8 % were achieved for Spiro-OMeTAD, TAT-TY3, and TAT-TY4, respectively.
ChemPhotoChemChemistry-Physical and Theoretical Chemistry
CiteScore
5.80
自引率
5.40%
发文量
165
期刊介绍:
Light plays a crucial role in natural processes and leads to exciting phenomena in molecules and materials. ChemPhotoChem welcomes exceptional international research in the entire scope of pure and applied photochemistry, photobiology, and photophysics. Our thorough editorial practices aid us in publishing authoritative research fast. We support the photochemistry community to be a leading light in science.
We understand the huge pressures the scientific community is facing every day and we want to support you. Chemistry Europe is an association of 16 chemical societies from 15 European countries. Run by chemists, for chemists—we evaluate, publish, disseminate, and amplify the scientific excellence of chemistry researchers from around the globe.