V. A. Shilov, M. A. Burmatova, V. D. Belyaev, D. I. Potemkin, P. V. Snytnikov
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The Influence of Platinum Additives on the Activity and Stability of Rh-Containing Catalyst for the Conversion of Diesel Fuel into Synthesis Gas
The influence of platinum additives on the properties of rhodium catalysts in the processes of steam reforming and autothermal reforming of diesel fuel was investigated. It was found that Rh/CZF was more active compared to the bimetallic sample Rh–Pt/CZF: the degree of fuel conversion in its presence was higher, and the concentration of reaction by-products was lower. The proposed two-zone Pt/CZF + Rh/CZF structured honeycomb catalyst demonstrated stable performance and high activity in the autothermal reforming of commercial diesel fuel. However, the presence of platinum in the frontal zone of the catalyst reduced its resistance to coking compared to the rhodium-containing sample. The results obtained are of practical significance in the development of efficient systems for the conversion of heavy hydrocarbons into synthesis gas.
期刊介绍：
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.
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