减少天然气压缩和生产过程中的碳排放

C. Carpenter
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引用次数: 0

摘要

本文由JPT技术编辑Chris Carpenter撰写,包含SPE 214974号论文 "新技术减少天然气压缩和生产设施的碳排放 "的要点,作者为SPE的John Guoynes、SPE的David Stiles和Axip能源服务公司的Cory Vail等。 目前已开发出一种不含化学物质的工艺,用于捕集天然气驱动压缩机和辅助天然气燃料生产设备产生的废气,同时具有占地面积小的特点。该工艺将二氧化碳和氮气从废气中分离出来,使二氧化碳在高压下排放,用于运输、封存或提高石油采收率。 北美有超过 50,000 台压缩机在输送天然气。它们大多由内燃机或涡轮机驱动。根据美国环境保护署的温室气体(GHG)报告计划,这些压缩机每年产生的二氧化碳当量估计超过 3000 万吨。随着《减少通货膨胀法案》的通过,温室气体减排政策的意义更加重大,该法案为企业投资未来的碳捕集利用和封存以及甲烷减排提供了支持。 对废气碳捕集系统进行了建模和分析,并对超临界二氧化碳(sCO2)废热回收发电循环进行了设计和优化。之所以选择这种循环,是因为与其他同类废热回收技术相比,它效率高、设计相对紧凑。初步工艺流程图是根据 30,000 马力大型往复式燃气发动机的条件绘制的。对几种工艺配置进行了研究;这些迭代在完整的论文中作了详细介绍。对这一发展过程的总结显示,迭代 1 到 3 表明,通过提高 sCO2 动力循环效率,功率有所提高。但是,这需要增加高压 sCO2 组件。在迭代 4 至 5 中,组件的简化将 sCO2 循环恢复为单一级联循环。sCO2 循环中的温度选择也提高了其效率。进入迭代 4 后,系统功耗降低了 20.7%。与迭代 4 相比,迭代 5 的性能略有下降。这是由于将更多的工作转移到了氨制冷机上,以及气体压缩机性能的适度恶化。迭代 5 并没有改善系统的功率要求。最终,迭代 4 是所评估的效率最高的循环,总体功率要求最低。 所开发的系统可捕捉天然气输送、油气生产和中游应用中常用的压缩设备和其他内燃设备排出的废气。该系统采用不含化学物质的低温设计,模块化占地面积小,可在大气压力下捕获大量废气。该技术可分离二氧化碳和氮气,利用废热产生足够的电力来驱动设备,并在超临界条件下高压排放捕集的二氧化碳,适用于 5000 至 20000 马力的压缩机站。该设计完全独立,安装在一个紧凑的撬包上,能够处理高达 7000 万 scf/D 的废气,同时还能从富烧驱动的压缩机、贫烧驱动的压缩机或涡轮机中提取液态二氧化碳。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Process Reduces Carbon Emissions From Natural Gas Compression and Production
This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper SPE 214974,“New Technology Reduces Carbon Emissions From Natural Gas Compression and Production Facilities,” by John Guoynes, SPE, David Stiles, SPE, and Cory Vail, Axip Energy Services, et al. The paper has not been peer reviewed. A chemical-free process has been developed to capture exhaust from natural gas drive compressors and supporting gas-fueled production equipment while featuring a small footprint. The process separates CO2 and nitrogen from exhaust, allowing the CO2 to be discharged at high pressure for transport, sequestration, or enhanced oil recovery. Over 50,000 compressors move natural gas in North America. Most are driven by either internal combustion engines or turbines. These compressors produce am estimate of more than 30 million tonnes of CO2 equivalent yearly, according to the US Environmental Protection Agency’s Greenhouse Gas (GHG) Reporting Program. The significance of GHG reduction policies has heightened with the passing of the Inflation Reduction Act, which provides support for companies investing in future carbon capture use and storage, along with methane reduction. Modeling and analysis of an exhaust-gas carbon capture system, and the design and optimization of a supercritical CO2 (sCO2) waste-heat-recovery power cycle, was performed. This cycle was chosen for its high efficiency and relatively compact design compared with competitive waste-heat-recovery technologies. The preliminary process-flow diagram was provided based on conditions for 30,000-hp large reciprocating gas engines. Several process configurations were investigated; these iterations are detailed in the complete paper. A summary of this development shows that Iterations 1 through 3 showed improvements in power through improving the sCO2 power-cycle efficiency. However, this came at the increase in high-pressure sCO2 components. A simplification of components returned the sCO2 cycle to a single cascaded cycle in Iterations 4 through 5. Temperature selection in the sCO2 cycle also improved its efficiency. Moving to Iteration 4 improved the system power requirement by 20.7%. Iteration 5 showed moderately reduced performance over Iteration 4. This was the result of shifting more duty to the ammonia chillers and a moderate worsening of performance in the gas compressor. Iteration 5 did not improve the power requirement of the system. Ultimately, Iteration 4 was the most-efficient cycle evaluated with the overall lowest power requirement. The system developed captures exhaust from compression and other internal combustion equipment commonly used in gas transmission, oil and gas production, and midstream applications. The system works with a chemical-free, cryogenic design with a small modular footprint to capture large volumes of exhaust gas at atmospheric pressure. This technology separates CO2 and nitrogen, generates enough power from waste heat to run the equipment, and discharges captured CO2 under high pressure at supercritical conditions for compressor stations of 5,000 to 20,000 hp. The design is fully self-contained and mounts on a compact skid package capable of handling up to 70 million scf/D of exhaust while extracting liquid CO2 from rich-burn driven compressors, lean-burn driven compressors, or turbines.
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