苯基偶氮-BODIPYs:通过 Pd 催化直接获取

Synlett Pub Date : 2024-04-06 DOI:10.1055/a-2301-2854
Sebastian H Röttger, Anjuli Birk, Burkhard Butschke, Peter G. Jones, D. Werz
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引用次数: 0

摘要

本文介绍了一种新型官能化 BODIPY 染料。利用 Buchwald-Hartwig 反应的既定程序,我们能够使用苯肼将 -chloro BODIPYs 转化为 α-azo-BODIPYs。我们对反应条件进行了优化,并改变了 BODIPY 核心和苯肼。记录了吸收光谱和发射光谱。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Phenylazo-BODIPYs: Direct Access via Pd-Catalysis

Phenylazo-BODIPYs: Direct Access via Pd-Catalysis
A new type of functionalized BODIPY dyes is described. Utilizing an established procedure for Buchwald-Hartwig reactions, we have been able to convert -chloro BODIPYs to α-azo-BODIPYs using phenylhydrazines. Optimization of the reaction conditions and variation of the BODIPY core and the phenylhydrazine were conducted. Absorption and emission spectra were recorded.
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