盐酸环境中的碳钢缓蚀剂:三甲氧苄啶-金属复合物的合成与表征

IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
Ali Abra Naser, Hassan Hammed, A. Alshemary, İsmail Seçkin Çardakli
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引用次数: 0

摘要

本研究的目的是制作并弄清常用缓蚀剂三甲氧苄啶(TM)的特性,然后将其用作一种抑制剂,通过吸附作用阻止碳钢在酸性介质(盐酸溶液)中的腐蚀。TM 也被称为流行的防腐剂。它可以添加到液体或气体中,以减缓化学反应的速度(在材料(通常是金属或合金)遇到流体时会发生腐蚀的情况下)。许多抗生素化合物,如 TM 衍生物、二水合二铁盐和四水合二铁盐,都含有能阻止金属腐蚀的活性基团。研究 TM 药物时使用了 XRD(X 射线衍射)、FTIR(傅立叶变换红外光谱)、UV-visible(紫外-可见光谱)和 TGA(热重分析)等光谱方法。同样,还引入了 OCP(开路电压)技术来评估抗腐蚀性和电流密度与电压的关系。最后,这项研究表明,由于 TM 药物的生产工艺简单,而且它们具有许多活性基团,能够与碳钢配位,因此可以建议将其作为腐蚀抑制剂使用。我们的研究表明,抑制剂浓度、溶液酸度和金属表面积的变化都有助于吸附。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Corrosion Inhibitors for Carbon Steel in HCl Environment: Synthesis and Characterization of Trimethoprim-Metal Complexes
This study is about making and figuring out what trimethoprim (TM), a popular corrosion inhibitor, is like and then using it as an inhibiting agent to stop corrosion in carbon steel in acid media (HCl solution) through adsorption. TM has also been known as the prevalent anti-corrosive agent. It can be added to a liquid or gas to slow the pace of a chemical reaction (in the case of a material – typically a metal or alloy – that corrodes when it encounters the fluid). Many antibiotic compounds, such as TM derivatives, diiron salt dihydrate, and diiron salt tetrahydrate, have active groups that can stop metal from corroding. Spectroscopic methods like XRD (X-ray difraction), FTIR (Fourier transform infrared spectroscopy), UV-visible (ultraviolet-visible spectroscopy), and TGA (thermogravimetric analysis) were used to study the TM drug. Similarly, the OCP (open circuit voltage) technique was introduced to assess the corrosion resistance and the density of current vs. voltage. Finally, this study revealed that TM drugs could be suggested for introduction as corrosion inhibitors due to their simple production and the fact that they have many active groups that exhibit the ability to coordinate with carbon steel. Our study revealed that changes in inhibitor concentrations, the solution's acidity, and the metal's surface area all contribute to adsorption.
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来源期刊
Materials Science
Materials Science 工程技术-材料科学:综合
CiteScore
1.60
自引率
44.40%
发文量
63
审稿时长
4-8 weeks
期刊介绍: Materials Science reports on current research into such problems as cracking, fatigue and fracture, especially in active environments as well as corrosion and anticorrosion protection of structural metallic and polymer materials, and the development of new materials.
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