利用共焦激光扫描显微镜评估用作生物燃料的托里菲尔荠菜秸秆的可磨性和微颗粒性能

Fuels Pub Date : 2024-04-11 DOI:10.3390/fuels5020009
O. S. Agu, L. Tabil, E. Mupondwa, Bagher Emadi
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摘要

本研究考察了热解和微波吸收器对改善生物质热化学特性和可磨性的综合影响,以用于热能、电力和增值产品。在台式微波反应器中对两种粉碎的荠菜秸秆(粉碎(筛网尺寸为 6.4 毫米)和切碎的生物炭添加量(0%、10% 和 20%))进行了托热,托热温度分别为 250 ℃ 和 300 ℃,惰性条件下的停留时间分别为 10、15 和 20 分钟,并进行了氮活化。烘干后,测定了几何平均颗粒和粒度分布、水分含量、灰分含量、体积密度和颗粒密度,并测定了烘干后的磨碎和切碎的生物炭和不含生物炭的磨碎性能值,并与未加工的荠菜秸秆进行了比较。结果表明,两种磨碎后的几何直径都有所减小。随着生物炭添加量的增加、停留时间的延长和热解温度的升高,研磨热解生物质所需的比能量明显降低。在 300 °C/20 分钟的条件下,碾磨后加入生物炭的托热荠菜秸秆的碾磨能量最低,为 34.30 千焦。用激光共聚焦扫描显微镜观察托烧荠菜秸秆颗粒的表面形态表明,生物炭添加量(>10%)和 250 °C 的托烧温度可造成严重的表面变形,超过 300 °C 时,会产生巨大的表面损伤和碳化重量分数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Grindability of Torrefied Camelina Straw and Microparticle Evaluation by Confocal Laser Scanning Microscopy for Use as Biofuel
This study examined the combined effect of torrefaction and microwave absorbers on improving biomass thermochemical characteristics and grindability for heat, power, and value-added products. Camelina straw in two grinds, ground (6.4 mm screen size) and chopped with biochar addition (0%, 10% and 20%), was torrefied in a bench-scale microwave reactor at torrefaction temperatures of 250 °C and 300 °C with residence times of 10, 15 and 20 min under inert conditions and nitrogen-activated. After torrefaction, the geometric mean particle and size distribution, moisture content, ash content, bulk and particle densities were determined, and the grinding performance values of torrefied ground and chopped with and without biochar were determined and compared with the raw camelina straw. The results showed that the geometric diameter decreased after torrefaction in both grinds. The specific energy required for grinding torrefied biomass decreased significantly with biochar addition, longer residence times, and increased torrefaction temperatures. Torrefied ground camelina straw with biochar after grinding had the lowest grinding energy of 34.30 kJ at 300 °C/20 min. The surface morphology by confocal laser scanning microscopy of torrefied camelina straw particles indicated that biochar addition (>10%) and a torrefaction temperature at 250 °C can create profound surface distortion, and beyond 300 °C, colossal surface damage and carbonized weight fractions were produced.
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