铁曼-伯朝拉盆地中泥盆纪-下弗拉斯年土著复合体石蜡油和沥青中的生物标志碳氢化合物和单个正烷烃的碳同位素

D. Bushnev, A. Ilchenko, L. V. Ogdanets, N. S. Burdel’naya
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摘要

--研究对象是蒂曼-佩乔拉盆地中泥盆世-下弗拉斯年地层复合体的沉积岩沥青质和石蜡油。我们研究了奥姆拉-利扎鞍部井芯中沥青质的生物标志烃组成和单个正构烷烃的碳同位素组成。研究结果与佩乔拉-科日瓦巨型油井南部石蜡油成分的类似数据进行了比较。采用岩石-评价热解方法研究了有机物的生成潜力和热成熟度。所研究的奥姆拉-利扎鞍部和佩乔拉-科日瓦巨型油井复合体岩石中有机物的成熟度与石油窗口相对应。关于正构烷烃碳同位素和生物标志烃组成的数据与石蜡油和主沉积岩群有机质之间可能存在的遗传关系并不矛盾。所研究的石蜡油和岩石沥青都含有早期洗脱的重排烷烃,这与其他含石油复合物的油类不同,而且正构烷烃的含量高于异构烷烃和多环生物标志物。在石油和沥青岩中,随着正构烷烃分子中碳原子数量的增加,13C 含量呈下降趋势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biomarker Hydrocarbons and Carbon Isotopes of Individual n-Alkanes in Paraffin Oils and Bitumens of the Middle Devonian–Lower Frasnian Terrigenous Complex of the Timan–Pechora Basin
––The objects of study were bitumens of sedimentary rocks and paraffin oils of the Middle Devonian–lower Frasnian terrigenous complex of the Timan–Pechora basin. We studied the composition of biomarker hydrocarbons and the carbon isotope composition of individual n-alkanes of bitumens from the cores of the wells of the Omra–Lyzha saddle. The results were compared with similar data on the composition of paraffin oils from the south of the Pechora–Kozhva megaswell. The generation potential and thermal maturity of organic matter were studied by the Rock-Eval pyrolysis method. The maturity of organic matter in the rocks of the studied complex in the Omra–Lyzha saddle and the Pechora–Kozhva megaswell corresponds to the oil window. Data on the carbon isotopy of n-alkanes and on the composition of biomarker hydrocarbons do not contradict the possible genetic relationship between paraffin oils and the organic matter of the host sedimentary complex. Both the studied paraffin oils and the rock bitumens contain early eluting rearranged hopanes atypical of oils of other petroliferous complexes and show high contents of n-alkanes relative to iso-alkanes and polycyclic biomarkers. The content of 13C tends to decrease with an increase in the number of carbon atoms in the n-alkane molecule in both oils and bitumen rocks.
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