Duvan Mendoza Lopez, Gilbert Teyssedre, L. Boudou, L. Berquez, Christian Laurent, Shinya Iwata, Tatsuo Takada
{"title":"通过光刺激放电、发光实验和量子化学计算得出的聚萘二甲酸乙二醇酯的电子特性","authors":"Duvan Mendoza Lopez, Gilbert Teyssedre, L. Boudou, L. Berquez, Christian Laurent, Shinya Iwata, Tatsuo Takada","doi":"10.1088/1361-6463/ad415b","DOIUrl":null,"url":null,"abstract":"\n The electronic properties of thin films of Poly(ethylene 2,6-naphthalate) –PEN, are investigated based on their photo-physical (optical absorption, photoluminescence) and electrical (space charge distribution, photo-stimulated discharge) behavior. Photo-stimulated currents are associated with optical absorption of the material leading to space charge dissipation as demonstrated by space charge distribution measurement. Based on this set of experimental results and quantum chemical calculation performed on PEN macromolecular system, we propose a new scheme for the electronic levels of PEN. This scheme allows understanding the mechanisms at play in photo-stimulated discharge. One of the main conclusions of our work is that photo-stimulated current measurements do not probe the energy level of traps. Detrapping of charges results from a two-step process where the photon energy is absorbed by chromophores that restitute a part of this energy to trapped charges through various mechanisms. Moreover, the new scheme allows discussing the components of the luminescence excited under different stresses, being electric field, electronic and UV irradiation, charge recombination and thermal activation.","PeriodicalId":507822,"journal":{"name":"Journal of Physics D: Applied Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electronic properties of polyethylene naphthalate as derived from photo-stimulated discharge, luminescence experiments and quantum chemical calculation\",\"authors\":\"Duvan Mendoza Lopez, Gilbert Teyssedre, L. Boudou, L. Berquez, Christian Laurent, Shinya Iwata, Tatsuo Takada\",\"doi\":\"10.1088/1361-6463/ad415b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n The electronic properties of thin films of Poly(ethylene 2,6-naphthalate) –PEN, are investigated based on their photo-physical (optical absorption, photoluminescence) and electrical (space charge distribution, photo-stimulated discharge) behavior. Photo-stimulated currents are associated with optical absorption of the material leading to space charge dissipation as demonstrated by space charge distribution measurement. Based on this set of experimental results and quantum chemical calculation performed on PEN macromolecular system, we propose a new scheme for the electronic levels of PEN. This scheme allows understanding the mechanisms at play in photo-stimulated discharge. One of the main conclusions of our work is that photo-stimulated current measurements do not probe the energy level of traps. Detrapping of charges results from a two-step process where the photon energy is absorbed by chromophores that restitute a part of this energy to trapped charges through various mechanisms. Moreover, the new scheme allows discussing the components of the luminescence excited under different stresses, being electric field, electronic and UV irradiation, charge recombination and thermal activation.\",\"PeriodicalId\":507822,\"journal\":{\"name\":\"Journal of Physics D: Applied Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Physics D: Applied Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1088/1361-6463/ad415b\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physics D: Applied Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1088/1361-6463/ad415b","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electronic properties of polyethylene naphthalate as derived from photo-stimulated discharge, luminescence experiments and quantum chemical calculation
The electronic properties of thin films of Poly(ethylene 2,6-naphthalate) –PEN, are investigated based on their photo-physical (optical absorption, photoluminescence) and electrical (space charge distribution, photo-stimulated discharge) behavior. Photo-stimulated currents are associated with optical absorption of the material leading to space charge dissipation as demonstrated by space charge distribution measurement. Based on this set of experimental results and quantum chemical calculation performed on PEN macromolecular system, we propose a new scheme for the electronic levels of PEN. This scheme allows understanding the mechanisms at play in photo-stimulated discharge. One of the main conclusions of our work is that photo-stimulated current measurements do not probe the energy level of traps. Detrapping of charges results from a two-step process where the photon energy is absorbed by chromophores that restitute a part of this energy to trapped charges through various mechanisms. Moreover, the new scheme allows discussing the components of the luminescence excited under different stresses, being electric field, electronic and UV irradiation, charge recombination and thermal activation.