贝壳萃取物对酸性介质中制革机械部件缓蚀潜力的研究

N. Oladunni, I. Anweting, A. Adetoro, Y. O. Ganiyu, E. Uwaiya
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摘要

在 313K 和 333K 的不同温度下,使用白千层壳的乙醇提取物作为抑制剂,研究了三元机械部件的缓蚀潜力。制革机械零件主要由低碳钢构成,其使用条件十分恶劣,包括暴露在潮湿、空气、酸、碱、盐和其他环境成分中,从而导致机械零件腐蚀。本研究的目的是利用植物(hyphaene thebaica 壳乙醇提取物)作为抑制剂,生成可测量和测试的数据,以控制腐蚀。具体方法包括:利用失重技术确定抑制剂的性能;利用动力学参数和吸附等温线(Langmuir 和 Temkin)确定金属与抑制剂的相互作用机制;利用暴露时间、贝壳提取物的植物化学成分、抑制剂浓度、介质浓度、温度、金属的初始重量以及每 2 小时金属的重量(共 6 小时)确定腐蚀过程。采用失重技术,在 6 小时内每 2 小时记录一次低碳钢的重量。浓度为 0.1 g/dm3 的植物抑制剂在 333 K 时的抑制效率最高(78.44%)。随着温度的进一步升高,抑制效率有所下降。绿色抑制剂具有环保、廉价和可生物降解的特点,因此被认为是一种有效的抑制剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
INVESTIGATION OF CORROSION INHIBITION POTENTIAL OF HYPHAENE THEBAICA SHELLS EXTRACT ON TANNERY MACHINES PARTS IN ACIDIC MEDIUM
Corrosion inhibition potential of ternary machine part was investigated by using ethanoic extract of hyphaene thebaica shells as inhibitor at different temperature of 313K and 333K. The Tannery machines part which are majorly made up of mild steels are subjected to harsh conditions, which include exposure to moisture, air, acid, base, salt and other environmental components that causes corrosion on machines’ parts. The aim of this research was to generate measurable and testable data towards the control of corrosion using plant (hyphaene thebaica shells ethanolic extracts) as inhibitor. This was accomplished through the determination of inhibitor’s performance by weight loss techniques, determination of metal-inhibitor interaction mechanism using kinetic parameters and adsorption isotherms (Langmuir and Temkin), the corrosion process through the use of exposure time, phytochemicals of the shell extracts, inhibitor concentration, media concentration, temperature, initial weight of metal and the weight of the metals in every 2 hours for a total of 6 hours. A weight loss technique was adopted and the weights of the mild steel were recorded every 2 hrs for 6 hrs. The highest inhibition efficiency (78.44%) was attained at 333 K for 0.1 g/dm3 concentration of the plant inhibitor. Inhibition efficiency decreased with further increase in the temperature. The green inhibitor was found to be effective because it is ecofriendly, inexpensive and biodegradable.
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