{"title":"通过表面改性提高硼的点火性能和反应速率","authors":"J. Liu, D. Wang, Zh. Zhang, F. Li","doi":"10.1134/s0010508224010131","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Boron is one of the most valuable fuels for rocket propellants. However, the boron oxide (B<sub>2</sub>O<sub>3</sub>) on the B surface has a high boiling point (1860°C), which hinders the contact between the internal active B and the oxidation component during the ignition and combustion process. As a result, the ignition energy of B is higher and the combustion reaction rate is lower. In order to improve the ignition performance and reaction rate of B, a surface modification of B by means of surface purification by a solvent, surface grafting, and making a composite with aluminum (Al), which has a high combustion temperature, has been prepared. Composite particles of B purified by ethanol and thick flake Al (TF-Al), denoted by EB/TF-Al, have the fastest reaction rate higher by 96.6% than that of raw B and TF-Al composite particles (RB/TF-Al). Surface grafting of B with TF-Al composite particles (KHB-3/TF-Al) ensure the minimum ignition energy, which is 29.1% lower than that of raw B. As the ignition performance and reaction rate of B are improved by means of surface modification, the performance of B-based rocket propellants is expected to be improved.</p>","PeriodicalId":10509,"journal":{"name":"Combustion, Explosion, and Shock Waves","volume":"40 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improvement of the Ignition Performance and Reaction Rate of Boron by Surface Modification\",\"authors\":\"J. Liu, D. Wang, Zh. Zhang, F. Li\",\"doi\":\"10.1134/s0010508224010131\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>Boron is one of the most valuable fuels for rocket propellants. However, the boron oxide (B<sub>2</sub>O<sub>3</sub>) on the B surface has a high boiling point (1860°C), which hinders the contact between the internal active B and the oxidation component during the ignition and combustion process. As a result, the ignition energy of B is higher and the combustion reaction rate is lower. In order to improve the ignition performance and reaction rate of B, a surface modification of B by means of surface purification by a solvent, surface grafting, and making a composite with aluminum (Al), which has a high combustion temperature, has been prepared. Composite particles of B purified by ethanol and thick flake Al (TF-Al), denoted by EB/TF-Al, have the fastest reaction rate higher by 96.6% than that of raw B and TF-Al composite particles (RB/TF-Al). Surface grafting of B with TF-Al composite particles (KHB-3/TF-Al) ensure the minimum ignition energy, which is 29.1% lower than that of raw B. As the ignition performance and reaction rate of B are improved by means of surface modification, the performance of B-based rocket propellants is expected to be improved.</p>\",\"PeriodicalId\":10509,\"journal\":{\"name\":\"Combustion, Explosion, and Shock Waves\",\"volume\":\"40 1\",\"pages\":\"\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-04-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Combustion, Explosion, and Shock Waves\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1134/s0010508224010131\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Combustion, Explosion, and Shock Waves","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1134/s0010508224010131","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
摘要 硼是火箭推进剂中最有价值的燃料之一。然而，硼表面的氧化硼（B2O3）沸点较高（1860°C），在点火和燃烧过程中阻碍了内部活性硼与氧化组分的接触。因此，B 的点火能量较高，燃烧反应速率较低。为了提高 B 的点火性能和反应速率，制备了一种通过溶剂表面净化、表面接枝以及与燃烧温度较高的铝（Al）复合等手段对 B 进行表面改性的方法。经乙醇提纯的 B 与厚片铝（TF-Al）的复合颗粒（EB/TF-Al）的反应速率最快，比原始 B 与 TF-Al 复合颗粒（RB/TF-Al）的反应速率高 96.6%。通过表面改性提高 B 的点火性能和反应速率，有望改善 B 基火箭推进剂的性能。
Improvement of the Ignition Performance and Reaction Rate of Boron by Surface Modification
Abstract
Boron is one of the most valuable fuels for rocket propellants. However, the boron oxide (B2O3) on the B surface has a high boiling point (1860°C), which hinders the contact between the internal active B and the oxidation component during the ignition and combustion process. As a result, the ignition energy of B is higher and the combustion reaction rate is lower. In order to improve the ignition performance and reaction rate of B, a surface modification of B by means of surface purification by a solvent, surface grafting, and making a composite with aluminum (Al), which has a high combustion temperature, has been prepared. Composite particles of B purified by ethanol and thick flake Al (TF-Al), denoted by EB/TF-Al, have the fastest reaction rate higher by 96.6% than that of raw B and TF-Al composite particles (RB/TF-Al). Surface grafting of B with TF-Al composite particles (KHB-3/TF-Al) ensure the minimum ignition energy, which is 29.1% lower than that of raw B. As the ignition performance and reaction rate of B are improved by means of surface modification, the performance of B-based rocket propellants is expected to be improved.
期刊介绍：
Combustion, Explosion, and Shock Waves a peer reviewed journal published in collaboration with the Siberian Branch of the Russian Academy of Sciences. The journal presents top-level studies in the physics and chemistry of combustion and detonation processes, structural and chemical transformation of matter in shock and detonation waves, and related phenomena. Each issue contains valuable information on initiation of detonation in condensed and gaseous phases, environmental consequences of combustion and explosion, engine and power unit combustion, production of new materials by shock and detonation waves, explosion welding, explosive compaction of powders, dynamic responses of materials and constructions, and hypervelocity impact.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
