{"title":"用二氧化钛和二氧化硅-二氧化钛薄膜涂覆发泡聚苯乙烯球体","authors":"Piotr Miądlicki, Piotr Rychtowski, Beata Tryba","doi":"10.1557/s43578-024-01319-3","DOIUrl":null,"url":null,"abstract":"<p>Expanded polystyrene spheres (EPS) were coated by SiO<sub>2</sub>–TiO<sub>2</sub> or TiO<sub>2</sub> for application as a fluidized bed in the photocatalytic reactor. Silica coating was realized by the sol–gel process carried out in a vacuum evaporator at 60–70 °C. The most uniform and thin layer of silica coating was obtained by the Stöber method based on the hydrolysis of tetraethyl orthosilicate (TEOS) catalysed by an ammonia solution. Effective TiO<sub>2</sub> coating was obtained by the immersion of EPS in the titania aqueous suspension and evaporation of water in a vacuum evaporator. Heating of EPS spheres coated by SiO<sub>2</sub>, TiO<sub>2</sub> or SiO<sub>2</sub>–TiO<sub>2</sub> at the temperatures of 120–140 °C resulted in a shrinkage of their volume. For the thick layer coating, a strong corrugation of EPS surface was observed. The photocatalytic tests showed, that highly corrugated surface of coated EPS slowed down ethylene decomposition, whereas a thin layer coating of both, SiO<sub>2</sub> and TiO<sub>2</sub> was advantageous.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":16306,"journal":{"name":"Journal of Materials Research","volume":"100 1","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Coating of expanded polystyrene spheres by TiO2 and SiO2–TiO2 thin films\",\"authors\":\"Piotr Miądlicki, Piotr Rychtowski, Beata Tryba\",\"doi\":\"10.1557/s43578-024-01319-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Expanded polystyrene spheres (EPS) were coated by SiO<sub>2</sub>–TiO<sub>2</sub> or TiO<sub>2</sub> for application as a fluidized bed in the photocatalytic reactor. Silica coating was realized by the sol–gel process carried out in a vacuum evaporator at 60–70 °C. The most uniform and thin layer of silica coating was obtained by the Stöber method based on the hydrolysis of tetraethyl orthosilicate (TEOS) catalysed by an ammonia solution. Effective TiO<sub>2</sub> coating was obtained by the immersion of EPS in the titania aqueous suspension and evaporation of water in a vacuum evaporator. Heating of EPS spheres coated by SiO<sub>2</sub>, TiO<sub>2</sub> or SiO<sub>2</sub>–TiO<sub>2</sub> at the temperatures of 120–140 °C resulted in a shrinkage of their volume. For the thick layer coating, a strong corrugation of EPS surface was observed. The photocatalytic tests showed, that highly corrugated surface of coated EPS slowed down ethylene decomposition, whereas a thin layer coating of both, SiO<sub>2</sub> and TiO<sub>2</sub> was advantageous.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\\n\",\"PeriodicalId\":16306,\"journal\":{\"name\":\"Journal of Materials Research\",\"volume\":\"100 1\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-04-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1557/s43578-024-01319-3\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Research","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1557/s43578-024-01319-3","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Coating of expanded polystyrene spheres by TiO2 and SiO2–TiO2 thin films
Expanded polystyrene spheres (EPS) were coated by SiO2–TiO2 or TiO2 for application as a fluidized bed in the photocatalytic reactor. Silica coating was realized by the sol–gel process carried out in a vacuum evaporator at 60–70 °C. The most uniform and thin layer of silica coating was obtained by the Stöber method based on the hydrolysis of tetraethyl orthosilicate (TEOS) catalysed by an ammonia solution. Effective TiO2 coating was obtained by the immersion of EPS in the titania aqueous suspension and evaporation of water in a vacuum evaporator. Heating of EPS spheres coated by SiO2, TiO2 or SiO2–TiO2 at the temperatures of 120–140 °C resulted in a shrinkage of their volume. For the thick layer coating, a strong corrugation of EPS surface was observed. The photocatalytic tests showed, that highly corrugated surface of coated EPS slowed down ethylene decomposition, whereas a thin layer coating of both, SiO2 and TiO2 was advantageous.
期刊介绍：
Journal of Materials Research (JMR) publishes the latest advances about the creation of new materials and materials with novel functionalities, fundamental understanding of processes that control the response of materials, and development of materials with significant performance improvements relative to state of the art materials. JMR welcomes papers that highlight novel processing techniques, the application and development of new analytical tools, and interpretation of fundamental materials science to achieve enhanced materials properties and uses. Materials research papers in the following topical areas are welcome.
• Novel materials discovery
• Electronic, photonic and magnetic materials
• Energy Conversion and storage materials
• New thermal and structural materials
• Soft materials
• Biomaterials and related topics
• Nanoscale science and technology
• Advances in materials characterization methods and techniques
• Computational materials science, modeling and theory
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