通过低温臭氧分解 1,3-二氧杂环庚烷合成含乙缩醛片段的多官能团 O 型化合物

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Doklady Chemistry Pub Date : 2024-04-13 DOI:10.1134/s0012500824600081

E. R. Belyaeva, Yu. G. Borisova, G. Z. Raskildina, R. M. Sultanova, S. S. Zlotsky

引用次数: 0

摘要

摘要通过对 1,3-二氧杂环庚烷进行低温臭氧分解，首次合成了 3,5-二氧杂环-1,7-庚二醛、3,5-二氧杂环-1,7-庚二醇和 1,3-二氧杂环-1,7-庚二苯甲酸衍生物。研究表明，根据分解条件的不同，臭氧分解的中间产物过氧化合物可以高选择性地生成相应的单个二醛、二醇和二酯。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins

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Synthesis of Polyfunctional O-Containing Compounds with Acetal Fragment by Low-Temperature Ozonolysis of 1,3-Dioxepins

Abstract

3,5-Dioxo-1,7-heptanedials, 3,5-dioxo-1,7-heptanediols, and derivatives of 1,3-dioxo-1,7-heptanediboxylic acid have been synthesized for the first time by the low-temperature ozonolysis of 1,3-dioxepins. It has been shown that intermediate ozonolysis products, peroxy compounds, depending on decomposition conditions can produce corresponding individual dialdehydes, diols, and diesters with high selectivity.

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来源期刊

Doklady Chemistry 化学-化学综合

CiteScore

1.20

自引率

12.50%

发文量

审稿时长

6-12 weeks

期刊介绍： Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.