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引用次数: 0
摘要
世界上有许多研究都在不断开发新的或改进现有的化工工艺,使其更加有效和环保。所描述的关于利用紫外线辐射和氧-臭氧混合物的耦合作用将环己烷或环己酮氧化成己二酸(而不是目前使用的 HNO3 氧化法)的研究正是这一趋势的一部分。气相色谱法用于确定工艺指标,如环己烷的转化率和对 AA 的选择性,在 25 oC 温度下,16 h 后的转化率超过 50%。
Coupled action of ozone and UV radiation towards obtaining adipic acid from cyclohexane/one
A lot of research is constantly underway in the world to develop new or improve the current processes of the chemical industry to make them more effective and environmentally friendly. The described research on the oxidation of cyclohexane or cyclohexanone to adipic acid with a coupled action of UV radiation and oxygen–ozone mixture, instead of the currently used oxidation with HNO3, is part of this trend. Gas chromatography was used to determine process indicators, such as cyclohexane conversion and selectivity to AA, which exceeded 50% at 25 oC, after 16 h. This method can also be used for the preparation of other dicarboxylic acids from cycloalkanes, which proves its universal character.
期刊介绍:
Polish Journal of Chemical Technology is a peer-reviewed, international journal devoted to fundamental and applied chemistry, as well as chemical engineering and biotechnology research. It has a very broad scope but favors interdisciplinary research that bring chemical technology together with other disciplines. All authors receive very fast and comprehensive peer-review. Additionally, every published article is promoted to researchers working in the same field.