浆料固相含量对凝胶注塑 Ti10Mo28Nb3Zr 合金工艺和性能的影响

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Z. Wu, Y. Xu, S. Zhao, Y. Cai, B. Lou
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引用次数: 0

摘要

摘要 为解决人体骨植入物的高弹性模量和生物毒性问题,以第一性原理实验计算并验证的低弹性模量成分Ti10Mo28Nb3Zr为原料,采用凝胶注射法和微波烧结法制备了具有低弹性模量和良好生物相容性的骨植入物钛合金。通过扫描电子显微镜、X 射线衍射、金相显微镜和压缩试验分析了固相含量对凝胶固化时间、收缩率、孔隙率、抗压强度和弹性模量的影响。当固相含量从 30% 增加到 45% 时,凝胶时间从 300 秒缩短到 205 秒。同时,轴向收缩率从 13.67% 降至 6.43%,径向收缩率从 13.11% 降至 6.18%。此外,抗压强度从 125 兆帕增加到 215 兆帕,弹性模量从 10.46 GPa 增加到 25.11 GPa。这些结果为通过凝胶注射成型制备医用生物钛合金及其在骨植入材料中的应用提供了依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effect of Slurry Solid phase Content on the Process and Properties of Gel Injection Moulding Ti10Mo28Nb3Zr Alloy

Effect of Slurry Solid phase Content on the Process and Properties of Gel Injection Moulding Ti10Mo28Nb3Zr Alloy

In order to solve the problems of high elastic modulus and biotoxicity of human bone implants, Ti10Mo28Nb3Zr, a component with low elastic modulus that had been calculated and verified by first-principles experiments, was used as raw material to prepare bone implant titanium alloy with low elastic modulus and good biocompatibility by means of gel injection and microwave sintering methods. The effects of solid content on gel curing time, shrinkage, porosity, compressive strength and elastic modulus of the materials were analyzed by scanning electron microscope, X-ray diffraction, metallographic microscope and compression tests. When the solid phase content increases from 30 to 45%, the gel time reduces from 300 to 205 s. This indicates that a higher solid phase content results in a shorter gel curing time. Meanwhile, the axial shrinkage decreased from 13.67 to 6.43%, and the radial shrinkage decreased from 13.11 to 6.18%. Moreover, the compressive strength increased from 125 to 215 MPa, the elastic modulus increased from 10.46 to 25.11 GPa. The results provide a basis for the preparation of medical bio-titanium alloy by gel injection molding and its application in bone implant materials.

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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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