通过苄胺介导的反应选择性地从 C60 中删除一个碳原子

IF 4.7 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Chemistry Frontiers Pub Date : 2024-04-10 DOI:10.1039/D4QO00449C

Yaqiong Wang, Yiran Wu, Yuming Yu, Jie Su, Yi Qiu and Liangbing Gan

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引用次数: 0

摘要

从球形骨架中选择性地删除碳原子，可产生norfullerene衍生物。在众多富勒烯衍生物中，诺富勒烯仍然相当罕见。在本研究中，我们发现苄胺能与一种具有 9 元孔口的[60]富勒烯混合过氧化物衍生物发生反应。添加了苄胺的产物经过随后的转化，得到了具有 11 个分子孔口的nor[59]富勒烯衍生物。碳原子缺失过程涉及分子内氢原子转移和脱羧序列。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Selective deletion of one carbon atom from C60 through benzylamine mediated reactions†‡

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Selective deletion of one carbon atom from C60 through benzylamine mediated reactions†‡

Selective deletion of carbon atom(s) from spherical skeletons results in norfullerene derivatives. Among the numerous fullerene derivatives, norfullerenes are still quite rare. In the present work benzylamine has been found to react with a [60]fullerene-mixed peroxide derivative with a 9-membered orifice. Subsequent transformations of the benzylamine-added product afforded a nor[59]fullerene derivative with an 11-membered orifice. The carbon atom deletion process involves an intramolecular hydrogen atom transfer and decarboxylation sequence.

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来源期刊

Organic Chemistry Frontiers CHEMISTRY, ORGANIC-

CiteScore

7.90

自引率

11.10%

发文量

686

审稿时长

1 months

期刊介绍： Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.