Fe3O4@NH2@Oxalic Acid：合成吡咯烷酮衍生物的便捷催化剂

IF 1.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of the Mexican Chemical Society Pub Date : 2024-02-01 DOI:10.29356/jmcs.v68i2.1910

Seyran Esmaeilzadeh, Davood Setamdideh, Fatemeh Ghanbary

{"title":"Fe3O4@NH2@Oxalic Acid：合成吡咯烷酮衍生物的便捷催化剂","authors":"Seyran Esmaeilzadeh, Davood Setamdideh, Fatemeh Ghanbary","doi":"10.29356/jmcs.v68i2.1910","DOIUrl":null,"url":null,"abstract":"Abstract. In this context, an amine-functionalized magnetite nanoparticle was synthesized from FeCl3•6H2O and 1, 2-ethylenediamine at 110 °C in ethylene glycol within 6 hours. Then, the obtained corresponding Fe3O4@NH2 was used for the preparation of Fe3O4@NH2@oxalic acid as organoacid-magnetic nanoparticles under ultrasonic irradiation at 60 °C within 4 hours. Its chemical structure was characterized by FT-IR, XRD, SEM, VSM, and EDAX spectra. The Fe3O4@NH2@oxalic acid nanoparticles were successfully used for the synthesis of pyrrolinones derivatives in excellent yields of the products (90-95 %) within 6-10 hours at room temperature in ethanol.","PeriodicalId":17377,"journal":{"name":"Journal of the Mexican Chemical Society","volume":null,"pages":null},"PeriodicalIF":1.1000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fe3O4@NH2@Oxalic Acid: A Convenient Catalyst for Synthesis of Pyrrolinone Derivatives\",\"authors\":\"Seyran Esmaeilzadeh, Davood Setamdideh, Fatemeh Ghanbary\",\"doi\":\"10.29356/jmcs.v68i2.1910\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract. In this context, an amine-functionalized magnetite nanoparticle was synthesized from FeCl3•6H2O and 1, 2-ethylenediamine at 110 °C in ethylene glycol within 6 hours. Then, the obtained corresponding Fe3O4@NH2 was used for the preparation of Fe3O4@NH2@oxalic acid as organoacid-magnetic nanoparticles under ultrasonic irradiation at 60 °C within 4 hours. Its chemical structure was characterized by FT-IR, XRD, SEM, VSM, and EDAX spectra. The Fe3O4@NH2@oxalic acid nanoparticles were successfully used for the synthesis of pyrrolinones derivatives in excellent yields of the products (90-95 %) within 6-10 hours at room temperature in ethanol.\",\"PeriodicalId\":17377,\"journal\":{\"name\":\"Journal of the Mexican Chemical Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Mexican Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.29356/jmcs.v68i2.1910\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Mexican Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.29356/jmcs.v68i2.1910","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

摘要本文以FeCl3-6H2O和1, 2-乙二胺为原料，在乙二醇中于110 ℃下6小时内合成了胺功能化磁铁矿纳米粒子。然后，将得到的相应 Fe3O4@NH2 用于制备 Fe3O4@NH2@草酸有机酸磁性纳米粒子。通过 FT-IR、XRD、SEM、VSM 和 EDAX 光谱对其化学结构进行了表征。Fe3O4@NH2@oxalic acid 纳米粒子被成功地用于合成吡咯烷酮衍生物，在乙醇中室温条件下 6-10 小时内，产物的收率极高（90-95%）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Fe3O4@NH2@Oxalic Acid: A Convenient Catalyst for Synthesis of Pyrrolinone Derivatives

Abstract. In this context, an amine-functionalized magnetite nanoparticle was synthesized from FeCl3•6H2O and 1, 2-ethylenediamine at 110 °C in ethylene glycol within 6 hours. Then, the obtained corresponding Fe3O4@NH2 was used for the preparation of Fe3O4@NH2@oxalic acid as organoacid-magnetic nanoparticles under ultrasonic irradiation at 60 °C within 4 hours. Its chemical structure was characterized by FT-IR, XRD, SEM, VSM, and EDAX spectra. The Fe3O4@NH2@oxalic acid nanoparticles were successfully used for the synthesis of pyrrolinones derivatives in excellent yields of the products (90-95 %) within 6-10 hours at room temperature in ethanol.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of the Mexican Chemical Society 化学-化学综合

CiteScore

2.00

自引率

0.00%

发文量

审稿时长

6-12 weeks

期刊介绍： The Journal of the Mexican Chemical Society (J. Mex. Chem. Soc.) is a scientific, blind, peer reviewed, and open access, free of charge publication that covers all areas of chemistry and its sub-disciplines (i.e. medicinal chemistry, natural products, electrochemistry, material science, computational chemistry, organic chemistry, bionirganic chemistry, etc). It is devoted to facilitating the worldwide advancement of our understanding of chemistry. It will primarily publish original contributions of research in all branches of the theory and practice of chemistry in its broadest context as well as critical reviews in active areas of chemical research where the author has published significant contribution. The J. Mex. Chem. Soc. is a quarterly publication which language of submission and publication is English. To be suitable for publication in J. Mex. Chem. Soc., manuscripts must describe novel aspects of chemistry, high quality of results and discussion an excellent bibliographic support, and contribute to the development of the field. Routine or incremental work are not suitable for publication in J. Mex. Chem. Soc. Authors are encouraged to send contributions in electronic form. Our online submission system guides you stepwise through the process of entering your article details and uploading your files.