意见:主流气溶胶研究是否应使用高分辨率差分迁移率分析仪?

J. Fernández de la Mora
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摘要

摘要。差示迁移率分析仪(DMA)是一种广泛用于测量亚微米气溶胶粒度分布的仪器。这里所说的高分辨率 DMA(HRDMA)是指在异常宽的鞘气流速 Q 范围内保持稳定流动的普通 DMA。然而,除了在 10 纳米以下的粒度范围内,它们并没有被广泛采用,通常是在新粒子形成研究中。在这里,我们要质疑一种普遍的观点,即 HRDMA 一定是复杂、笨重和昂贵的机器,主要用于主流气溶胶研究之外的奇特应用。相反,气溶胶研究中的许多核心研究都可以利用 HRDMA 进行,而且在粒度范围、分辨率、灵敏度和测量速度方面都有相当大的优势。希望 DMA 制造商能够迎接挑战,开发出复杂程度和成本与当今商用仪器相当的商用 HRDMA,供气溶胶科学家广泛使用,同时大大提高灵活性和性能。本文讨论了仍需克服的一些技术挑战,如高流量冷凝计数器探测器的开发以及高样品和鞘气流速的控制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Opinion: Should high-resolution differential mobility analyzers be used in mainstream aerosol studies?
Abstract. Differential mobility analyzers (DMAs) are widely used instruments to measure the size distributions of submicron aerosols. High-resolution DMAs (HRDMAs) are defined here as plain DMAs maintaining a steady flow over an unusually broad range of sheath gas flow rates Q. HRDMAs, first developed by Georg Reischl's group, have existed for a long time. However, they have not been widely adopted, except in the size range below 10 nm, often in new particle formation studies. Here we question the commonly held view that HRDMAs are necessarily complex, bulky and expensive machines, mainly of interest in exotic applications outside mainstream aerosol research. Rather, many studies central to aerosol research could be carried out with HRDMAs with considerable advantage in size range, resolution, sensitivity and measurement speed. DMA manufacturers will hopefully take the challenge of developing commercial HRDMAs of complexity and cost comparable to those of today's commercial instruments, adapted for broad use by aerosol scientists, though with greatly improved flexibility and performance. Some of the technical challenges that still need to be overcome are discussed, such as the development of high-flow condensation counter detectors, and the control of high sample and sheath gas flow rates.
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