{"title":"水热法合成的还原氧化石墨烯/二氧化钛纳米复合薄膜的光学研究","authors":"Linda I. Mohi, A. F. Abdulameer","doi":"10.30723/ijp.v22i1.1197","DOIUrl":null,"url":null,"abstract":"The growing need for unique optical properties in the manufacturing of electronic devices has led the world to the field of hybrid materials and their composites. In this study, a simple physical technique was used to successfully manufacture hybrid nanocomposites containing nanoparticles of titanium dioxide (TiO2) and reduced graphene oxide (rGO) from tetrabutyl titanate (TBT) and graphene oxide (GO) powder using the hydrothermal method. For two hydrothermal treatment times (12h and 24h), various samples were created: TiO2, rGO, and TiO2/rGO nanocomposites thin films. Fourier transformer infrared (FTIR) spectra of the samples gave clear evidence for the reduction of GO and the engagement of Ti with reduced graphene by the formation of a Ti-O-C bond. The measurement of the energy band gap obtained by the photoluminescence spectrometer shows a decrease in the energy band gap for all samples after the hydrothermal reaction time increases, for the composite, the band gap decreases to 2.65 eV and 2.64 eV.","PeriodicalId":517619,"journal":{"name":"Iraqi Journal of Physics","volume":"158 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optical Investigation of Reduced Graphene Oxide / Titanium Dioxide Nanocomposite Thin Films Synthesized by Hydrothermal Method\",\"authors\":\"Linda I. Mohi, A. F. Abdulameer\",\"doi\":\"10.30723/ijp.v22i1.1197\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The growing need for unique optical properties in the manufacturing of electronic devices has led the world to the field of hybrid materials and their composites. In this study, a simple physical technique was used to successfully manufacture hybrid nanocomposites containing nanoparticles of titanium dioxide (TiO2) and reduced graphene oxide (rGO) from tetrabutyl titanate (TBT) and graphene oxide (GO) powder using the hydrothermal method. For two hydrothermal treatment times (12h and 24h), various samples were created: TiO2, rGO, and TiO2/rGO nanocomposites thin films. Fourier transformer infrared (FTIR) spectra of the samples gave clear evidence for the reduction of GO and the engagement of Ti with reduced graphene by the formation of a Ti-O-C bond. The measurement of the energy band gap obtained by the photoluminescence spectrometer shows a decrease in the energy band gap for all samples after the hydrothermal reaction time increases, for the composite, the band gap decreases to 2.65 eV and 2.64 eV.\",\"PeriodicalId\":517619,\"journal\":{\"name\":\"Iraqi Journal of Physics\",\"volume\":\"158 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Iraqi Journal of Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.30723/ijp.v22i1.1197\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Iraqi Journal of Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30723/ijp.v22i1.1197","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
随着制造电子设备对独特光学特性的需求日益增长,世界进入了混合材料及其复合材料领域。本研究采用一种简单的物理技术,利用水热法从钛酸四丁酯(TBT)和氧化石墨烯(GO)粉末中成功制备出含有二氧化钛(TiO2)纳米颗粒和还原氧化石墨烯(rGO)的混合纳米复合材料。在两种水热处理时间(12 小时和 24 小时)内,制备出了不同的样品:TiO2、rGO 和 TiO2/rGO 纳米复合薄膜。样品的傅立叶变换红外光谱(FTIR)清楚地证明了 GO 的还原以及 Ti 与还原石墨烯通过形成 Ti-O-C 键的结合。光致发光光谱仪对能带间隙的测量表明,水热反应时间延长后,所有样品的能带间隙都有所减小,复合材料的能带间隙分别减小到 2.65 eV 和 2.64 eV。
Optical Investigation of Reduced Graphene Oxide / Titanium Dioxide Nanocomposite Thin Films Synthesized by Hydrothermal Method
The growing need for unique optical properties in the manufacturing of electronic devices has led the world to the field of hybrid materials and their composites. In this study, a simple physical technique was used to successfully manufacture hybrid nanocomposites containing nanoparticles of titanium dioxide (TiO2) and reduced graphene oxide (rGO) from tetrabutyl titanate (TBT) and graphene oxide (GO) powder using the hydrothermal method. For two hydrothermal treatment times (12h and 24h), various samples were created: TiO2, rGO, and TiO2/rGO nanocomposites thin films. Fourier transformer infrared (FTIR) spectra of the samples gave clear evidence for the reduction of GO and the engagement of Ti with reduced graphene by the formation of a Ti-O-C bond. The measurement of the energy band gap obtained by the photoluminescence spectrometer shows a decrease in the energy band gap for all samples after the hydrothermal reaction time increases, for the composite, the band gap decreases to 2.65 eV and 2.64 eV.