罗利-波利模型中产生负熵的确切例子

Charles T. Drucker, Joseph D. Peterson
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摘要

众所周知,罗利-波利模型并不能保证热力学上的一致性,但热力学上不一致预测的确凿事 例尚未公布。此外,该问题的来源(及其历史背景)可能并不广为人知。这项工作提供了额外的背景信息,以及在与实验相关的流动中产生负熵的确切例子,包括对可回收应变等实验可测量量的影响的讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Definite example of negative entropy production in the Rolie Poly model
While it is known that the Rolie Poly model is not guaranteed to be thermodynamically consistent, definite examples of a thermodynamically inconsistent prediction have not yet been published. Additionally, the source of the problem (and its historical context) may not be widely known. This work provides additional background information and a definite example of negative entropy production in an experimentally relevant flow, including a discussion of the implications in terms of an experimentally measurable quantity like recoverable strain.
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